Abstract
Collisional and photoabsorption properties of electronically excited molecular hydrogen are studied by means of selective excitation of the (,) double minimum state. The level of the inner well of the , state is populated by two-photon absorption of ArF* laser radiation at 193 nm. Intracavity prisms are used to narrow the laser linewidth and tune the laser to excite single rotational levels selectively. Both and HD have been excited in this manner, but the absorption lines are outside the laser tuning range. The population densities of the , rovibrational levels are measured by monitoring the near-infrared , fluorescent emission. The ,-state radiative lifetime, electronic and rotational collisional relaxation rates, and photoionization cross section at 193 nm are measured. The large electronic quenching cross section (∼100 ) observed is compared to a Born approximation calculation of inelastic scattering in the (,) system and is found to be due to collisional population of the state. Observations of vacuum-ultraviolet emission support this conclusion. The rotational relaxation cross sections are ≲0.2 Å for , but are much larger in HD (∼10 ).
- Received 31 July 1979
DOI:https://doi.org/10.1103/PhysRevA.21.607
©1980 American Physical Society