Convergence of the Density Gradient Expansion for Atoms

K. A. Brueckner and J. D. Perez
Phys. Rev. A 2, 2161 – Published 1 November 1970
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Abstract

The inhomogeneity correction to the correlation energy of an electron gas is added to the Thomas-Fermi energy-density functional for atoms. The density is significantly modified only inside a radius of the order Z13×105 Bohr radii. This does not reduce the density gradient sufficiently to make the expansion convergent.

  • Received 19 June 1970

DOI:https://doi.org/10.1103/PhysRevA.2.2161

©1970 American Physical Society

Authors & Affiliations

K. A. Brueckner and J. D. Perez

  • Institute for Pure and Applied Physical Sciences, University of California, San Diego, La Jolla, California 92037

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Issue

Vol. 2, Iss. 5 — November 1970

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