Abstract
A molecular approach employing quantum close-coupling calculations has been utilized to calculate the cross sections for the reactions for at a collision energy of 0.04 eV. The calculations employ exact asymptotic coupling matrix elements and the recently measured term splittings for the sequence. The cross sections are found to rise rapidly with increasing to a maximum cross section of the order at values of 7-12. For larger values of , the cross sections decrease with increasing . The magnitude of the maximum cross section is found to roughly correlate to the electron scattering length of the noble-gas perturbing atom. The theoretical calculations compare well with recent experimental measurements of Gallagher, Edelstein, and Hill.
- Received 7 July 1976
DOI:https://doi.org/10.1103/PhysRevA.15.631
©1977 American Physical Society