The Infrared Dispersion of Carbon Dioxide

Hugh M. Smallwood
Phys. Rev. 41, 164 – Published 15 July 1932
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Abstract

The term in the dispersion equation of carbon dioxide corresponding to the bending vibration (λ=14.91μ) has been calculated from the assumption that this dispersion is due to interaction of the electric vector of the light wave and permanent dipole moments associated with the carbon-oxygen valence bonds. The calculation indicates a magnitude of 1.17×1018 e.s.u. for these dipoles, which is shown to be in agreement with the value to be expected from the measured moment of acetone.

  • Received 31 May 1932

DOI:https://doi.org/10.1103/PhysRev.41.164

©1932 American Physical Society

Authors & Affiliations

Hugh M. Smallwood

  • Mallinckrodt Chemical Laboratory, Harvard

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Vol. 41, Iss. 2 — July 1932

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