The yield cross sections ${\sigma }_{{{\mathrm{H}}_2}^{+}}$, ${\sigma }_{{\mathrm{H}}^{+}}$, and ${\sigma }_{\mathrm{H}}$ for production of fast ${\mathrm{H}}_2^{+}$ and ${\mathrm{H}}^{+}$ ions and H atoms resulting from the ionization and dissociation of fast ${\mathrm{H}}_2$ molecules in single collisions with ${\mathrm{H}}_2$ gas molecules have been measured in the 6- to 120-keV energy range (collision velocity 0.7 to 3.2×${10}^8$ cm/sec). The neutral primary beam contained a fraction of H atoms which was determined by proportional counter analysis. Secondary particles produced by the H atoms in the primary beam were determined in separate H beam experiments and subtracted from the composite (H,${\mathrm{H}}_2$) neutral beam data to yield the production of secondaries due to ${\mathrm{H}}_2$ primaries alone. Cross section ${\sigma }_{{{\mathrm{H}}_2}^{+}}$ increases monatonically from 0.5 to 2.0 ${\mathrm{\AA }}^2$ in the energy range 6 to 120 keV while ${\sigma }_{{\mathrm{H}}^{+}}$ increases from 0.28 ${\mathrm{\AA }}^2$ at 7.5 keV to a maximum of 0.70 ${\mathrm{\AA }}^2$ at 50 keV. Cross section ${\sigma }_{\mathrm{H}}$, measured only at 10 keV, was found to have an approximate value of 2.5 ${\mathrm{\AA }}^2$ based on an assumed shape of the H atom angular distribution at small angles. The results are compared with data on a number of collision processes in the same velocity range involving various species of hydrogen ions and H atoms incident on ${\mathrm{H}}_2$ gas molecules.

• Received 9 January 1964

DOI:https://doi.org/10.1103/PhysRev.134.A1226