Relationship between cooling rate, microstructure evolution, and performance improvement of an Al–Cu alloy prepared using different methods

The relationship between the cooling rate and microstructure evolution and the performance improvement of an Al–4.5 wt% Cu alloy prepared using different casting methods was investigated. The microstructure evolution, solute element distribution, and mechanical properties of specimens prepared using different cooling rates were systematically investigated using multi-scale optical microscopy, scanning electron microscopy, transmission electron microscopy, tensile testing, and hardness testing. Upon increasing the cooling rate from 1.65 to 117.3 K s−1, the average grain size, secondary dendrite arm spacing, and width and area fraction of eutectic phases significantly decreased, and the density of the precipitated phase, super-saturation degree of solute elements, and mechanical properties improved. Through a combination of grain-boundary, solid-solution, and precipitation strengthening, the cooling rate indirectly affected the mechanical properties of the heat-treated alloy sheets. The Al−4.5 wt% Cu alloy prepared by twin-roll casting under a cooling rate of 117.3 K s−1 exhibited a strength between 145.33 and 321.79 MPa and an elongation of 11.65%, demonstrating its potential as a high-performance aluminium alloy.


Introduction
The ageing process refers to a metal or alloy workpiece held at a specific temperature for a period after solution treatment. Generally, after ageing heat treatment, the properties change with holding time, the strength and hardness increase, while the plasticity, toughness, and internal stress decrease. Age-hardened Al-Cu alloys are widely used in the transportation and aerospace industries, because of their advantages of light weights, high strengths, good heat resistances, easy processing abilities, and recyclabilities [1,2]. As a near-net shape processing technique, twin-roll casting (TRC) is a continuous casting technique used to produce metallic sheets directly from molten metal, which minimises the need for subsequent secondary processing. This process offers a number of significant advantages over conventional direct-chill (DC) casting, including a shorter production period, reduced energy consumption, a lower scrap rate, and higher added value [3][4][5]. If the metallurgical and technological challenges for producing alloys with high alloy content and wide solidification intervals can be overcome, it is likely that TRC will become one of the most promising technologies of the 21st century.
Aluminium alloys with high elemental content and large solidification intervals produced by the traditional semi-continuous DC casting technique suffer from the negative consequences of additional residual crystalline phases, serious macro/micro-segregation, hot cracking, and poor casting performance [6,7]. Consequently, the extensive application of traditional ingot metallurgy to fabricate high-quality aluminium alloys has been limited. It is well known that many of the mechanical properties of materials are affected by their microstructures, with a finer grain size being beneficial to improve the ductility [8,9], mechanical properties, hardness, corrosion non-equilibrium solidification and solid-state transformation will directly determine the optimisation of the composition/process design and properties. Therefore, the use of an appropriate cooling rate is crucial for improving the mechanical properties of alloys with wide solidification intervals.
Previous studies on the effect of the cooling rate on the microstructure and properties have been limited to the near-equilibrium cooling rate range. In the present work, Al−4.5 wt% Cu alloy sheets were prepared with wide solidification intervals using different casting methods, and the relationship between the cooling rate and microstructure evolution, mechanical properties, and solute distribution during different solidification processes were explored. This work provides technological support for the industrial manufacture of highperformance aluminium alloys with competitive advantages via a novel, short, and low-cost process, opening the door for further development of TRC based on a sub-rapid solidification technique in industry.

Melting and casting of experimental alloy
The Al−4.5 wt% Cu alloy was prepared using pure Al (99.7 wt%) and an Al−50 wt% Cu master alloy melted into a graphite crucible in an intermediate frequency furnace. After the aluminium ingot was melted completely, the melt was transferred to an electric resistance furnace and heated at 710°C for 1 h; next, the melt was degassed with 0.2 wt% C2Cl6 followed by removal of the slag. An Al-Ti-B (0.4 wt%) grain refiner was also added to the melt, which was regularly stirred to achieve a homogenised melt for the casting experiment [3].
As shown in figure 1, the alloy was cast into 6-mm-thick slabs using three different methods: sand mould, water-cooled Cu mould, and TRCs, to investigate the relationship between the cooling rate and microstructure evolution and the mechanical properties of Al-4.5 wt% Cu alloy. The dimensions of the solidification samples were 6 mm×200 mm×400 mm with a pouring temperature of 710°C. For twin-roll casting, a horizontal twin-roll caster with two rolls (500 mm in diameter and 500 mm in width) was used. The thicknesses of the roll sleeve, maximum roll gap, and maximum separation rolling force were 50 mm, 50 mm, and 1000 kN, respectively. The initial cast-rolling speed, melt temperature, casting nozzle width, and cooling water pressure were 1.2 m min −1 , 710°C, 200 mm, and 0.4 MPa, respectively.

Determination of cooling curves during different casting methods
Cooling curves were obtained for the thermal analysis of all the samples using a thermal analyser and K-type thermocouples. The thermocouples were inserted into a stainless-steel sheath and connected to a high-speed data acquisition system. The data signals were recorded every 100 ms in all experiments. During the casting experiment using sand and water-cooled Cu moulds, the thermocouples were inserted into the mid-section at the heights of each mould (150 mm from the bottom of the mould). To improve the reliability of the collected data, before each series of experimental tests, the thermocouples were calibrated by melting and solidification of high-purity aluminium, and two thermocouples were inserted into each group of samples at the same time to prevent experimental failure caused by thermocouple damage. The thermal analyser indicated the cooling curves, temperature, and time on the monitor in real time for instant observation. Time-temperature data were recorded at a frequency of 10 readings per second, and the cooling curve was plotted using Origin 9.0 software. The parameters of solidification, including the cooling rate, nucleation temperature, solidification intervals, and solidification time, were determined by data processing.

Microstructural characterization and mechanical property tests
The as-cast alloys were milled, hot-rolled, cold-rolled to 1 mm, solution-treated at 535°C for 6 h and quenched in water at 25°C. Next the alloys were aged at 200°C for 6 h in an air cushion furnace. Specimens for microstructural observations and tensile tests were cut from the central area of the sheets. Characterisation of the constituent phases was performed by X-ray diffraction (XRD) with a Cu Kα source operating at 25 kV and 50 mA and a scanning rate of 5°min −1 . The metallographic samples were prepared by standard mechanical polishing and etched with 25 g l −1 hydrofluoric acid solution to form an anode coating. The microstructure was examined using a Zeiss polarising optical microscope (OM). The morphologies of the constituent phases with different specimens were examined using field-emission scanning electron microscopy coupled with X-ray energy dispersive spectroscopy (EDS). The secondary dendrite arm spacing (SDAS) and average grain size of α-Al were measured using the linear interception method. Furthermore, transmission electron microscopy (TEM) specimens were cut from the end of the tensile specimen. Vickers hardness tests were performed on the polished specimens (load: 5 N, holding time: 10 s). Subsequently, the average value of five groups of measurements was recorded. Finally, tensile tests were performed on an AG-X100 kN tensile tester at room temperature with a deformation speed of 1 mm min −1 . Figure 2(a) presents the thermal analysis of the solidification curves of the as-cast alloys prepared using different casting methods. The solidification time varied significantly with the casting method selected, indicating that the average cooling rate was considerably affected by the heat-transfer capabilities of the different casting moulds. As observed in figure 2(b), the use of the first derivative improved the accuracy of determining the characteristics of the solidification cooling curves. This benefit was not realised in the original solidification curves. The first derivative of the cooling curve was numerically equal to the slope of the solidification curve, which represented the average cooling rate of the metal during solidification.

Thermal analysis of cooling curves
As previously reported [25,26], the inflection points (Points 1 and 6 in figure 2(b)) on the first derivative curve represent the formation of a new phase. There were two obvious inflection points, indicating that two phase transformations occurred during solidification, the formation of α-Al dendrite and eutectic phases. The results indicate that the α-Al dendrites were formed in the early stages; stages one, two, and three represent the nucleation, growth, and thickening of α-Al dendrites, respectively, and the eutectic phases were formed during the late stage of solidification. The corresponding cooling rates were calculated for the different casting methods: the cooling rates of the sand mould, water-cooled Cu mould, and TRC methods were 1.65, 5.70, and 117.3 K s −1 , respectively.

As-cast microstructure
The microstructures of the as-cast alloys prepared with different cooling rates are shown in figure 3. As observed in figure 3(a), under the condition of a slow cooling rate in sand mould casting, the as-cast microstructure of the Al-4.5 wt% Cu alloy is coarse and uneven, and the grain size ranges from tens to hundreds of microns. The alloy was mainly composed of the primary α-Al phase and Al2Cu eutectic phase that are distributed along the grain boundary. The secondary dendrite spacing was observed to be large. As observed in figure 3 (c), with an increasing cooling rate during solidification, the primary α-Al phase changes from a coarse phase to a fine phase   for the water-cooled Cu mould casting. This transformation resulted from the increase in the nucleation rate caused by large undercooling; at the same time, the growth and coarsening of grains after nucleation was inhibited. One may observe from figures 3(e) and (f) that with a higher cooling rate, the dendrite structure become more evident, indicating that increasing the cooling rate promotes the formation of dendrites. Although the grain size showed no obvious change, the SDAS clearly decreased.
To characterise the microstructures of the Al-4.5 wt% Cu alloys prepared with different cooling rates, XRD patterns and DSC curves were obtained, as shown in figure 4. The XRD data reveal that the as-cast alloys mainly contained α-Al and Al2Cu phases and with an increasing cooling rate, the α-Al peak shifted. Furthermore, with an increasing cooling rate, the moving speed of the liquid-solid interface clearly increased, more Cu were captured and dissolved in the α-Al matrix, and the lattice of α-Al was distorted. In addition, less Cu remained to form the Al2Cu eutectic phase; thus, the peak intensity of the Al2Cu phases was significantly changed.
As shown in figures 4(c)-(e), the DSC results were consistent with the conclusions drawn from the XRD patterns. At approximately 545°C, obvious endothermic peaks appear for the three groups of specimens at the same time, indicating that the eutectic phases were dissolved at this temperature. The area around the endothermic peak in figure 4 is proportional to the precipitation amount of the Al2Cu phases. The precipitation of the Al2Cu phase was inhibited and decreased with an increasing cooling rate. The endothermic peak area (i.e., enthalpy change) was calculated using Origin 9.0 software, and the results in figure 4(f) indicated that upon increasing the cooling rate, the content of the Al2Cu eutectic phases decreased and the peak area decreased from 11.34 J g −1 for sand mould casting, to 6.22 J g −1 and 4.57 J g − for water-cooled Cu mould casting and the TRC method, respectively; the ratio of the peak areas was 2.48:1.36:1.00. Figure 5 presents backscattered scanning electron microscopy (SEM) images of the as-cast Al-4.5 wt% Cu alloys prepared using different cooling rates. It is well established that the as-cast microstructure contains α-Al and Al2Cu phases and that the cooling rate has a significant effect on the grain size, the width of eutectic phases, and the secondary dendritic arm spacing. In addition, the cooling rate also affects the area fraction of Al2Cu eutectic phases. As the cooling rate increases from 1.65 to 117.3 K s −1 , the average width of the eutectic phases decreases from 25.94 to 5.28 μm, and the average area fraction of Al2Cu eutectic phase decreases from 4.4% to 1.8%. The relationship between the cooling rate and eutectic phase is plotted in figure 5(d). The measured values of the secondary dendritic arm spacing and width of eutectic phases are presented in figure 6. With an increasing cooling rate, the average grain size decreased from 309.5 μm with the sand mould to 185.7 μm with the water-cooled Cu mould to 148.6 μm using the TRC method. In addition, the average secondary dendritic arm spacing decreased from 53.4 μm with the sand mould, to 26.3 μm with the watercooled Cu mould, and to 7.33 μm using the TRC method. A 40% reduction in grain size and 86.3% reduction in SDAS were observed upon increasing the cooling rate from 1.65 to 117.3 K s −1 . From the above analysis, the higher cooling rate affects not only the grain size and secondary dendrite spacing, but also the area fraction and width of eutectic phases.  The SEM morphologies and corresponding distributions of alloying elements of as-cast Al-4.5 wt% Cu alloys produced with a cooling rate of 1.65 K s −1 are shown in figure 7. In addition to Al, the alloying elements mainly consisted Cu and a small amount of Fe and O. It can be clearly observed that the eutectic phases at the grain boundary had a lamellar distribution. According to the XRD patterns in figure 4(a) and EDS analysis in figure 7, these eutectic phases are mainly composed of α-Al and Al2Cu; the weight percentages of Cu and Fe in the eutectic phase with different morphologies in the grain boundary are 5.54% and 2.33%, respectively, as shown in figure 7. The Al:Cu atomic ratio of 68.41%:31.59% is close to 2:1. Thus, the grey rod phase could be assumed to be the Al2Cu phase.
Line-scanning images of different solute elements in the grains and grain boundaries of the as-cast alloy produced at cooling rates of 1.65 and 117.3 K s −1 are presented in figure 8. As observed in figures 8(a) and (b), the non-equilibrium eutectic phase is lamellar for the cooling rate of 1.65 K s −1 using the sand mould. The lamellar thickness was in the range of 1-2 μm. When the cooling rate was 117.3 K s −1 for TRC, the width of the eutectic phases at the grain boundary was obviously refined, being reduced from approximately 10 to 5 μm, and the non-equilibrium eutectic phase was dispersed on the grain surface or grain boundary in the form of particles. Furthermore, as observed, with an increasing cooling rate, the Cu content in the α-Al matrix clearly increased, with the average peak content of 334.87-349.69 at 1.65 K s −1 increasing to 894.92-1000.8 at 117.3 K s −1 . It indicates that the increase of cooling rate caused the content of Cu in the crystal increase nearly three times. Figure 9 presents SEM micrographs of the Al-4.5 wt% Cu alloys after homogenisation treatment at 500°C for 10 h, showing the effect of cooling rate on the eutectic phase transformation. After homogenisation treatment, the grain boundaries became fine and clear, and fewer crystalline phases remained on the grain boundary, indicating that most of the eutectic phases decomposed and dissolved into the α-Al matrix. As observed in figures 5 and 6, with an increasing cooling rate, the SDAS, width of the eutectic phase, and area fraction decrease. These fine eutectic phases at the grain boundary were more likely to decompose during homogenisation treatment, and the time required for complete homogenisation of the alloy decreased.

Eutectic phase transformation after homogenization treatment
Using Al−4.5 wt% Cu alloy as an example, during the ageing kinetics precipitation process, the precipitation sequence is known to be supersaturated solid solution (SSSS)→GPI→GPII→Al2Cu. GPI is a segregation region of Cu atoms in the {100} Al plane. These phases are coherent, semi-coherent, and non-coherent with Al matrix, respectively.
TEM images of Al-4.5 wt% Cu alloy with different cooling rates are presented in figure 10, and the results indicated that the cooling rate can significantly affect the densities and sizes of the precipitated phases. For a cooling rate of 1.65 K s −1 with the sand mould, the precipitate density was relatively low (see figure 10(a)). For the TRC, when the cooling rate was increased to 117.3 K s −1 , the precipitate density significantly increased (see figure 10(e)). The results showed that a higher cooling rate increases the dislocation density in the matrix, that in turn provides more nucleation sites for the subsequent precipitation of precipitates.
The number and lengths of precipitates increased with an increasing cooling rate, and the length distributions of precipitates at cooling rates of 1.65 to 117.3 K s −1 were also measured. The results in figure 11 show that the average length of the precipitates decrease from 259.18 μm to 94.68 μm upon increasing the cooling rate from 1.65 to 117.3 K s −1 . Thus, it could be concluded that the higher cooling rate of TRC accelerates   age-hardening and promotes the precipitation for the same ageing time. From the above analysis, a higher cooling rate not only improved the dislocation density in the matrix but also increased the number and densities of precipitates and decreased the average length of the precipitates.

Mechanical properties of T6-treated alloys
As demonstrated in figure 12, the age-hardening curves of the age-treated alloys at 200°C for different times with different cooling rates were measured. In the early stage, the average hardness significantly increased with increasing ageing time. When the ageing time reached 16 h, the hardness reached the highest peak-aged hardness of 107.13 HV for the TRC alloys. After reaching the peak-aged point, the hardness began to gradually decrease with increasing ageing time. For the alloy prepared at a cooling rate of 117.3 K s −1 using TRC, the time to reach the peak hardness was 16 h. However, for the alloy prepared at a cooling rate of 1.65 K s −1 for sand mould casting, the time to reach the peak hardness was 20 h. The results indicated that a higher cooling rate promoted the age-hardening behaviour of the alloy and reduced the ageing time to reach the peak hardness.
To better understand the effect of cooling rate on the mechanical properties, the T6-treated alloys were investigated, and the results are presented in figure 13. When the cooling rate is increased from 1.65 to 117.3 K s −1 , the strength, elongation, and area fraction of the T6-treated alloys increase rapidly from 109.64 MPa, 263.18 MPa, and 9.98% to 145.33 MPa, 321.79 MPa, and 11.65%, respectively. The mechanism consisted of two parts: (1) Higher cooling results in smaller grains and higher dislocation density. When plastic deformation occurs, more dislocations can move in more grains. Moreover, the plastic deformation becomes more uniform, simultaneously resulting in higher strength and elongation. (2) The area fraction of eutectic phases and the size of intermetallic compounds decrease with an increasing cooling rate, and the distribution becomes more uniform, which correspondingly increases the elongation.

Effect of the cooling rate on the as-cast microstructure
The growth morphologies and characteristic sizes of dendrites are determined by thermal diffusion, solute diffusion, interfacial energy, liquid convection, and interfacial atomic dynamics during solidification. After the alloy composition is given, the composition can be controlled by modifying the control parameters of solidification. The growth rate and temperature gradient are the control parameters for the directional solidification characteristic size, and the cooling rate and undercooling degree are the control parameters for free dendrites. For cast rolling, sub-rapid solidification is achieved by dynamic quenching. When the alloy composition is constant, the main factor affecting the SDAS is the cooling rate.
In reference [26], the following relationship between the SDAS and solidification time and cooling rate was determined: Image-pro software was used to measure the SDAS at different positions of the samples for different cooling rates, and the average values of 10 groups of data were calculated. The measured data are presented in table 1. A theoretical model for the relationship between the SDAS and cooling rate was established using the data in table 1. The undetermined coefficients in the calculation formula of simultaneous equations were used, with values of 71.04 and −0.57, respectively. The modified model of the relationship between the SDAS and cooling rate was as follows: As observed in equation (1), the theoretical index is −1/3. Because of the differences in the alloy composition system and cooling rate test method, this index will have certain differences. In this study, the experimental index is −0.57, as shown in equation (2). From the growth analysis of the secondary dendrite arm, the SDAS will be greatly increased with an increasing cooling rate.
The final solidification region of the alloy is the triangular grain-boundary region and the inter-dendritic region, where the intermetallic compounds are formed. With an increasing cooling rate, the primary dendrite α-Al grains shrink, the number of grain boundaries increases, and the SDAS decreases significantly. These indicate a smaller size, narrower width, and more uniform distribution of the inter-crystalline eutectic phases when compared to those of the initial case. The shorter dendrite arm spacing reduced the holding time for the subsequent heat treatment, resulting in a more fully dissolved eutectic phase and improved the overall mechanical properties of the alloy sheet.

Mechanism of cooling rate on mechanical properties
From the tensile test results in figure 13, as the cooling rate increases from 1.65 to 117.3 K s −1 , the yield strength and elongation increase from 109.64 to 145.33 MPa and 9.98% to 11.65%, respectively. The strengthening mechanism involves a combination of grain-boundary, solid-solution, and precipitation strengthening. From the results in figures 3, 8, and 10, increasing the cooling rate leads to grain refinement, an increase in the supersaturated solid solution degree of solute elements, and a clear enhancement of the age-hardening kinetics.
The results indicate that under the multiple effects of these mechanisms, the strength as well as plasticity and toughness of the material can be improved. Therefore, the yield strength of the material can be expressed as follows [13,27]: Here, σy is the yield strength measured from the tensile test, σ0 is the friction stress during the experiment, which is approximately 5.5 MPa [28,29]; Δσ gb is the yield strength increase obtained by grain-boundary strengthening, Δσ ss is the yield strength increase obtained by solid-solution strengthening from the solutes of Cu; Δσ pr is the yield strength increase obtained by precipitation strengthening; ky is the Hall-Petch coefficient and the values are as described in Ref. [30]; d is the average diameter of the grains, as shown in figure 3, M is the mean orientation factor, G is the shear modulus, b is the magnitude of the Burgers vector, ε is the lattice strain, and c is the concentration. Figure 14 presents a schematic illustration of the solid phase transformations at different cooling rates. With an increasing cooling rate, the grain size decreases and the number of grain boundaries increases, which increases the resistance to dislocation movement (see figure 14(a)); the number and width of the eutectic phase at the grain boundary decrease; and the initial network distribution of the eutectic phase disperses into a pointlike and discontinuously distributed eutectic phase. The decrease in the amount of the eutectic phase indicates that more solute elements are solids dissolved into the matrix (see figure 14(b)). In addition, with increasing the solute content in the matrix, the driving force for the second-phase precipitation increases. For smaller precipitates, the distribution is more uniform (see figure 14(c)). The coupling effect of these mechanisms leads to an improvement in the strength and hardness of the alloy sheet, and plastic deformation to be more uniform.

Effect of cooling rate on the super-saturation
From the above discussion, it is apparent that the cooling rate affects the age-hardening behaviour, and that different mechanical properties can be obtained after heat treatment. This mechanism can be explained by the effect of the cooling rate on the super-saturation of solute elements in the matrix. The results in figure 6(b) show that the cooling rate has a direct effect on the SDAS; a faster cooling rate result in a shorter SDAS. As observed in figures 9(b) and (f), after the same homogenisation treatment, the decomposition degree of the eutectic phase and super-saturation of solute elements are different. To clarify the relationship between super-saturation and SDAS, the dissolution time of the Al2Cu eutectic phases is calculated using the following formula [31]: Here, T, Q, L, D 0 , and R denote the homogenisation temperature, activation energy of diffusion, dendritic spacing, a constant, and the gas constant, respectively. By substituting Q (Cu)=136.8 kJ mol −1 , D 0 (Cu)=0.084 cm 2 s −1 , and R=8.31 J/(mol K) into Eq. (4), the relationship between the dendritic spacing and homogenisation time curves of the Al-Cu alloy is obtained. The calculated results are presented in figure 15. The homogenisation time rapidly increases with increasing dendritic spacing. For example, for a dendritic spacing of 32.5 μm at a cooling rate of 117.3 K s −1 , the complete homogenisation time of the alloy sheet is 500°C×7.1 h. Upon increasing the dendrite spacing to 58.4 μm at a cooling rate of 1.65 K s −1 , the homogenisation time increases to 23.5 h. Under such conditions, some large eutectic phases are only partially dissolved after homogenisation treatment and some eutectic phases remain at the grain boundaries, as shown in figure 9(b). Therefore, it can be reasonably assumed that after homogenisation treatment, the super-saturation of the matrix at a cooling rate of 1.65 K s −1 is significantly lower than that at a cooling rate of 117.3 K s −1 . This assumption is also consistent with the as-cast alloy line-scanning results in figure 8.
According to the conclusions of previous studies and the above analysis of this paper, we can see that the cooling rate has a significant effect on the microstructures and mechanical properties of different metals or alloys. Higher cooling rates result in the formation of finer grains [32], the thinning of intermetallic phase of β-Mg17Al12 at the grain boundaries [33], the increase in dislocation density [34], and uniform distribution of second-phase particles [35]. Additionally, rapid cooling can significantly reduce the SDAS in the as-cast microstructure. After solution treatment, the smaller eutectic phase of the alloy with smaller dendrite spacing can be rapidly decomposed to realise the accelerated dissolution of solute elements. Therefore, the precipitation behaviour will be promoted and more complete, resulting in improved strength, hardness, and other mechanical properties.

Conclusion
In the present work, a systematic study of Al-4.5 wt% Cu cast alloys was completed and the effect of the cooling rate on the microstructure and mechanical properties of the alloys after casting and heat treatment was investigated. The relationship between the microstructural evolution and performance improvement was studied, and the mechanisms of grain refinement and super-saturation of solute elements were discussed. The main conclusions are as follows: (1) Upon increasing the cooling rate from 1.65 to 117.3 K s −1 , the microstructure was clearly refined. The average grain size, SDAS, and area fraction decreased from 309.5 to 148.6 μm, 53.4 to 7.33 μm, and 4.4% to 1.8%, respectively.
(2) Upon increasing the cooling rate, the amount of eutectic phase at the grain boundary was clearly reduced, indicating that more solute elements were dissolved into the α-Al matrix, and the peak strength of Cu in the α-Al matrix increased by a factor of nearly three, from 334.87 at 1.65 K s −1 to 1000.8 at 117.3 K s −1 .
(3) With an increasing cooling rate, the homogenisation time was shortened from 23.5 h at 1.65 K s −1 to 7.1 h at 117.3 K s −1 , and the coarse eutectic phases formed at a lower cooling rate remained after homogenisation. After ageing precipitation, the density of the precipitated phase increased, and the precipitate size became finer and more uniform than that of the precipitate before ageing precipitation.
(4) An increase in the cooling rate was helpful for improving the mechanical properties of T6-treated alloys.
With an increasing cooling rate, the time required for the alloy to reach peak hardness was reduced from 20 h at 1.65 K s −1 to 16 h at 117.3 K s −1 . In addition, the strengths increased from 109.64 MPa and 263.18 MPa to 145.33 MPa and 321.79 MPa, respectively. Moreover, the elongation increased from 9.98% to 11.65%.