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Study of the effect of crystallization conditions on the structure of polyurethane block copolymer based on poly-ε-caprolactone diol and isophoron diisocyanate

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Published under licence by IOP Publishing Ltd
, , Citation M A Gorbunova et al 2020 IOP Conf. Ser.: Mater. Sci. Eng. 848 012047 DOI 10.1088/1757-899X/848/1/012047

1757-899X/848/1/012047

Abstract

In the paper a study of isothermal crystallization kinetics of polyurethane on the basis of poly-ε-caprolactone diol, isopforon diisocyanate and 1, 4-butanediol is presented. The process of isothermal crystallization in the temperatures range from -15 to 30ºC was studied by DSC method. Analysis of total melting enthalpy and degree of crystallinity of the polyurethane allows to obtain material with one or two melting points of polyester block at desired temperature. These results will help in design of new thermoplastic elastomers with one- or two-stage shape memory effect.

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