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Optimal control of electrostatic self-assembly of binary monolayers

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Published 27 May 2009 Published under licence by IOP Publishing Ltd
, , Citation N V Shestopalov et al 2009 New J. Phys. 11 053014 DOI 10.1088/1367-2630/11/5/053014

1367-2630/11/5/053014

Abstract

A simple macroscopic model is used to determine an optimal annealing schedule for self-assembly of binary monolayers of spherical particles. The model assumes that a single rate-controlling mechanism is responsible for the formation of spatially ordered structures and that its rate follows an Arrhenius form. The optimal schedule is derived in an analytical form using classical optimization methods. Molecular dynamics simulations of the self-assembly demonstrate that the proposed schedule outperforms other schedules commonly used for simulated annealing.

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10.1088/1367-2630/11/5/053014