Magnetic extended x-ray absorption fine structure at the edges of 3d elements

We report normal and magnetic extended x-ray absorption fine-structure (EXAFS) measurements made on 30 ML Fe films on Cu(001) substrates at the edges. The magnetic EXAFS at the L edges of 3d metals is particularly important as it can be used to probe the magnetism of the d states. Magnetic EXAFS oscillations were detected up to 500 eV above the edge, corresponding to in k-space. Over such a large range, we were able to see long-wavelength wiggles and separate them from Fe nearest-neighbour backscattering and the fast oscillations that had been previously seen. It is shown that without using any deconvolution procedure, a meaningful analysis can be performed despite the interference of the and edges. The experimental data were compared with the results of multiple-scattering calculations, and this enabled us to assign all of the features in both the normal and the magnetic EXAFS Fourier transforms to various single- and multiple-scattering paths. Also, there was found to be less temperature-dependent damping for magnetic EXAFS as than for the normal EXAFS between 75 K and 300 K.