Abstract
I investigate dense coding with a general mixed state on the Hilbert space Cd ⊗ Cd shared between a sender and receiver. The following result is proved. When the sender prepares the signal states by mutually orthogonal unitary transformations with equal a priori probabilities, the capacity of dense coding is maximized. It is also proved that the optimal capacity of dense coding χ* satisfies ER(ρ) ≤ χ* ≤ ER(ρ) + log2 d, where ER(ρ) is the relative entropy of entanglement of the shared entangled state.