Statistics of experiments on cluster formation and transport in a gravitational field

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Published under licence by IOP Publishing Ltd
, , Citation A S Myerson and A F Izmailov 1993 J. Phys. D: Appl. Phys. 26 B123 DOI 10.1088/0022-3727/26/8B/019

0022-3727/26/8B/B123

Abstract

Metastable state relaxation in a gravitational field is investigated in the case of noncritical binary solutions. A relaxation description is presented in terms of the time-dependent Ginzburg-Landau formalism for a nonconserved order parameter. A new ansatz for solution of the corresponding partial nonlinear stochastic differential equation is discussed. It si proved that, for the supersaturated solution under consideration, the metastable state relaxation in a gravitational field leads to formation of solute concentration gradients due to the sedimentation of subcritical solute clusters. The pure discussion of the possible methods to compare theoretical results and experimental data related to solute sedimentation in a gravitational field is presented. It is shown that in order to describe these experiments it is necessary to deal both with the value of the solute concentration gradient and with its formation rate. The stochastic nature of the sedimentation process is shown.

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10.1088/0022-3727/26/8B/019