Ferromagnetic ferric oxide

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Published under licence by IOP Publishing Ltd
, , Citation E F Herroun and E Wilson 1928 Proc. Phys. Soc. 41 100 DOI 10.1088/0959-5309/41/1/309

0959-5309/41/1/100

Abstract

A brief account is given of work relating to the above subject that has been published during the past eight years. The authors confirm the observation by Messrs. Sosman and Posnjak that lepidocrocite, but not göthite, yields on dehydration a strongly ferromagnetic ferric oxide. As all the specimens of lepidocrocite examined contained three or four per cent. of manganese oxide, they suggest that this substance may be an essential constituent of this crystalline form of the hydrate. They find that the temperature at which the ferromagnetic oxide is permanently transformed into the common paramagnetic kind is largely dependent upon its mode of preparation.

A table showing the magnetic force at which the magnetic permeability and susceptibility reach their maximum values as well as the coercive force and remanent magnetisation is given for different kinds of magnetic ferric oxide and for magnesium and copper ferrites in the form of compressed rectangular bars. Comparative figures are given for two varieties of natural magnetite. Curves are also given showing the variation of permeability with field strengths ranging from 25 to 1300 C.G.S. units.

Although copper ferrite has a higher maximum permeability than ordinary precipitated magnetic oxide of iron, it falls far below that of the purer forms of native magnetite. Analyses of several natural magnetites are given, and the high or low values of the susceptibility of the ferric oxide resulting from their oxidation are attributed to the presence or absence of impurities, particularly magnesia which forms a magnetic ferrite.

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10.1088/0959-5309/41/1/309