Efficient dopants for ZrNiSn-based thermoelectric materials

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Published under licence by IOP Publishing Ltd
, , Citation Heinrich Hohl et al 1999 J. Phys.: Condens. Matter 11 1697 DOI 10.1088/0953-8984/11/7/004

0953-8984/11/7/1697

Abstract

Four efficient n-type dopants have been found for ZrNiSn-based thermoelectric materials. These are Nb or Ta at the zirconium sites, and Sb or Bi at the tin sites. No suitable dopant was found for the nickel sites. In a alloy, a power factor of and a thermal conductivity of were measured at 300 K, resulting in a dimensionless figure of merit ZT = 0.12. These values are increased to and at 700 K.

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