Elastic and vibrationally inelastic slow collisions: H + H2, H+ + H2

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Published under licence by IOP Publishing Ltd
, , Citation Predrag S Krstic and David R Schultz 1999 J. Phys. B: At. Mol. Opt. Phys. 32 2415 DOI 10.1088/0953-4075/32/10/310

0953-4075/32/10/2415

Abstract

We report on a comprehensive study of the scattering of hydrogen atoms on the ground electronic surface of hydrogen molecules in the range of centre of mass energies 0.1-100 eV. Differential and integral elastic cross sections, the related transport cross sections, and vibrationally inelastic cross sections starting from both ground and excited vibrational states, are calculated using a fully quantal, coupled-channel approach in a truncated vibrational basis set, while the rotational dynamics of H2 is treated with the infinite order sudden approximation prescription. For comparison and to highlight the major physical mechanisms revealed in these collisions, a parallel study is carried out for scattering of protons on hydrogen molecules.

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