A neutron diffraction study of the nuclear and magnetic structure of BiFeO3

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, , Citation A J Jacobson and B E F Fender 1975 J. Phys. C: Solid State Phys. 8 844 DOI 10.1088/0022-3719/8/6/015

0022-3719/8/6/844

Abstract

The atom positions in antiferromagnetic and ferroelectric BiFeO3 have been obtained by profile analysis of powder neutron diffraction data collected ant 4.2K and 293K. The sublattice magnetization also determined at 4.2K, has been used to obtain a covalency parameter sum, Asigma 2+2Api 2+As2=13.4+or-0.5%. An experiment to obtain further information about the neutron magnetic form factor, by complete separation of the nuclear and magnetic contributions using polarization analysis, is described.

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10.1088/0022-3719/8/6/015