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Dipole-dipole interaction and internal vibrations in molecular crystals

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Published under licence by IOP Publishing Ltd
, , Citation F Bogani and V Schettino 1978 J. Phys. C: Solid State Phys. 11 1275 DOI 10.1088/0022-3719/11/7/018

0022-3719/11/7/1275

Abstract

The contribution of long-range dipole-dipole forces to the energy of the internal modes in a series of molecular crystals has been evaluated using the Weald-Kornfeld summation method. Comparison with experimental infrared observations such as LO-TO and Davydov splittings, gas to crystal frequency shifts, band shapes, transition dipole moments, phonon bandwidths, is discussed.

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10.1088/0022-3719/11/7/018