Recoil effects on Doppler-free lineshapes in non-linear spectroscopy

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, , Citation J H Shirley 1980 J. Phys. B: Atom. Mol. Phys. 13 1537 DOI 10.1088/0022-3700/13/8/010

0022-3700/13/8/1537

Abstract

Previously derived equations describing recoil effects in saturated absorption by a gas of two-level atoms or molecules are solved numerically for the case of standing plane-wave excitation and large Doppler broadening. The numerical techniques and accuracy estimates are discussed briefly. The lineshapes obtained are well approximated by the superposition of two Lorentzian functions whose width, heights, and separation parametrise the lineshape. The dependence of these parameters on saturation, recoil splitting, and relaxation rates is described and compared with corresponding results in the rate equation approximation and in the weak-probe-beam approximation. Saturation broadening depends strongly on these latter approximations, but very little on recoil splitting. When multiphoton processes are retained in the equations, increasing saturation causes a slight decrease in the fitted separation of the peaks. The ratio of the heights of the two Lorentzians is closely related to the ratio of relaxation rates for the level populations.

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10.1088/0022-3700/13/8/010