Development and characterization of agglomerated abrasives based on agro-industrial by-products

ABSTRACT The present work deals with the valorization of agro-industrial by-products to realize bonded abrasives. Four by-products were studied because of their wide availability and mechanical properties: palm nuts shells (Elaeis guineensis), Coco Nucifera shells, fruit kernels of Canarium schweinfurthii and fruit kernels of Raffia Vinifera. The Oliver and Pharr hardness and Young’s modulus of the raffia cores are obtained by instrumented macro indentation, giving the values 101 MPa and 1.82 GPa, respectively. The development of the abrasive wheels was based on the experimental method of full factorial design at 2 levels. Porosity, hardness, resilience, material removal rate and wear were determined. Leeb 280 HL hardness shoe sole material was used for tribological testing. The optimal formulations have 20% binder content and 1 mm grain size of the four agro-industrial by-products used with a higher material removal rate and a longer life than commercial grinding wheels. These results presage their use in the shoe industry and abrasive disc huskers. GRAPHICAL ABSTRACT


Introduction
Bonded abrasives play a significant role in the industry (Goossens, Cherif, and Cahuc 2013). Used for polishing, grinding, sharpening, cutting or reshaping operations, they consist of grains agglomerated in a vitrified or organic binder (Jamrozik, Strzemiecka, and Voelkel 2018). Among the organic binders, epoxy resin can be used because, it is compatible with plant products (Jiang et al. 2015;Nagatani et al. 2019;Sabaa and Fahad 2018). Epoxy resin has a density of 1.24 g/cm 3 to 1.30 g/cm 3 , a viscosity of up to 3300 MN/m 2 , a coefficient of thermal expansion of 55 × 10 6 / 0 C and a curing shrinkage of 1% to 2% (Suresha et al. 2006). One of the characteristics of abrasives is their hardness; it plays a significant role in the grinding process (Nadolny, Sutowski, and Herman 2015). The topography of grinding wheels facilitates the analysis and characterization of grinding processes, given the orientation of abrasive grains in the wheels (Arunachalam and Ramamoorthy 2007;Chakrabarti and Paul 2008). Abrasive grains can be of natural origin such as corundum, garnet (Calligaro et al. 2006;Jani et al. 2016), emery (Syreyshchikova and Yu Pimenov 2017), flint (Nadolny, Sutowski, and Herman 2015;Sestier 2010) or synthetic origin such as aluminum oxide (Herman and Markul 2004); (Jamrozik et al. 2020;a;Jamrozik et al. 2020 b), silicon carbide (Odior and Oyawale 2010;Odior1 and Oyawale 2013), cubic boron nitride (Huang et al. 2021;Toenshoff, Grabner, and Zinngrebe 2007) or diamond for specific applications due to its high hardness although its production cost is higher (Watanabe et al. 2010). To date, the raw material allowing to obtain abrasives faces a certain number of limits which are mainly translated by progressive exhaustion of the deposits of alluvial quarries in the course of exploitation and especially with constraints related to environmental protection tend to limit certain exploitations. Therefore, artificial abrasives remain an effective solution although their implementation requires enormous technical means (Jamrozik, Strzemiecka, and Voelkel 2018), which are difficult to produce locally. It becomes necessary to find alternative materials to conventional abrasives. Plant products like of hard cores or shells can be an interesting alternative in a context where the valorization of waste or by-products from agriculture remains a major research challenge (Prevot 2010).
The availability of these by-products can be assessed from the cultivation of their plants. Oil production from palm nuts (Elaeis guineensis) is estimated at 230,000 tons annually in Cameroon (Iyabano 2014). According to the Food and Agriculture Organization, Cocos nucifera nuts reached 62 million tons in 2013, with a cultivable area of close to 12 million hectares (Kodjo et al. 2015). The fruit production of Canarium schweinfurthii (Engl) is estimated at 1000 tons per harvest season in West Cameroon (Njoukam and Peltier 2002).
Previous studies evaluated the physical and mechanical characteristics of these plant by-products (Kodjo et al. 2015;Koungang et al. 2020;Morino et al. 2020;Ndapeu et al. 2013;Njeugna et al. 2016;Sikame Tagne et al. 2014;Stanislas et al. 2020), while some others used it at reinforcement charge composite materials Lagel et al. 2015;Oliveira Filho et al. 2020;Pathmanaban, Musharath Aalam, and Sr 2019). While many studies have focused on the stem and fibers of raffia vinifera (Mbou et al. 2017;Sikame Tagne et al. 2014, very few, if any, studies have focused on the fruit and specifically on its pit. Moreover, work on bonded abrasives based on hard shells and cores has not been the subject of in-depth studies to date. This work aims to elaborate and characterize agglomerated abrasives based on palm nut shells, coconut shells, Canarium schweinfurthii cores and Raffia cores, in order to study the influence of the parameters related to the nature and the number of constituents on the abrasive properties. The mechanical properties of raffia fruit cores were determined to complete the information on the characterization of the by-products used. Then this study was followed by the development of abrasive materials on the factorial design model, and finally, tests were conducted to evaluate the influence of parameters on the abrasive properties.

Mechanical characterization of raffia fruit cores
Data on the hardness and Young's modulus of palm nut shells, coconut shells and canarium cores (Lucas et al. 2009;Morino et al. 2020) can be found in the literature. However, raffia fruit kernels have not yet been subjected to the same tests. Thus, the raffia fruit cores were harvested in the western region of Cameroon and subjected to physical, thermal and mechanical characterization. The mechanical characterization of the raffia fruit allowed the determination of the hardness and Young's modulus according to the Oliver and Pharr method based on the contact equations. This method has the advantage of characterizing the surface materials and the mechanical properties of the material interfaces without destroying the bodies (Kermouche, Saint-Etienne, and Bergheau 2014). The experimental macro indentation bench was developed at the laboratory and made it possible to carry out similar work on shells . The cut specimens (Figure 1) are parallelepipedic in shape with dimensions of 15 mm x 10 mm x 10 mm.
Two measurement points were selected on each of the faces of 11 specimens at room temperature. The indentation curve (load/unload) was obtained by increasing the 5 kg masses 10 times with a dwell time of 15 s, until a total load of 500 N was obtained thus complying with ISO 14,577 (Kaupp and Reza Naimi-Jamal 2011). The hardness and modulus of elasticity of the indented raffia cores are based on the contact equations of Hertz and the method of Oliver and Pharr (Oliver and Pharr 1992). The fit of the discharge curve is obtained by Equation 1.
where P is the instantaneous load, h is the displacement of the indenter (indentation depth), hf is the residual indentation depth, Pm and hm are, respectively, the maximum load and displacement, m is a constant that can be adjusted according to experimental data, being m = 1 for a spherical indenter (Oliver and Pharr 1992). The initial slope of the discharge curve, S, known as contact stiffness, is calculated at the point of maximum applied load using Equation 2.
The reduced modulus of elasticity E R of the material is determined from the stiffness S calculated at the maximum depth on the discharge curve and the contact area Ac (Kossman, Chicot, and Iost 2017). For spherical indenters, the relationship that links E R to A C (Fischer-Cripps 2000) is obtained from Equation 3.
E R is also related by Young's modulus and Poisson's ratio of the indenter (Ei, νi) and the material (E, ν) by the relation (4).
The Young's modulus E presented in equation (5) is obtained from Equation 4 Oliver and Pharr introduce the contact depth hc over which the indenter is in contact with the material surface as shown in Equation 6.
ε is a recommended value that depends on the geometry of the indenter, which takes the value of 0.75 for a sphere (Pharr and Oliver 2004). Knowing this geometry, the contact surface area Ac can be estimated by Equation 7.
where R is the radius of the spherical indenter and a is the radius of the projected contact. The hardness (H) is determined by the relationship (8) from the maximum applied load (Pm) and the contact area (Ac).

Experimental design model
Four plant by-products were used in the formulation of the abrasive wheels: palm nut shells, coconut shells, canarium schweinfurthii fruit kernels and raffia fruit kernels. They were cleaned in a distilled water bath. Drying was carried out in a Memmert UF110 oven at a temperature of 105°C for 24 hours (Enih et al. 2017). They were then introduced into a grinder for transformation into fragments. Particles with a particle size between 1 mm and 0.8 mm for large sizes (P20) and between 0.2 mm and 0.160 mm (P80) were obtained by sieving according to the FEPA standard (Elaissi et al. 2020). The binder used is an epoxy resin available in the local market. Our scientific approach is based on two level full factorial experimental designs. The geometry of the abrasive grains is more or less spherical after grinding and sieving. The determining factors are the percentage of resin and the size of the abrasive grains. The mathematical model presented in Equation 12 is a first-degree model developed by (Goupy 1990).
• y is the response variable; • x1 is the level assigned to the percentage of resin • x2 is the level assigned to the grain size • a 0 is the value of the response at the center of the study domain; • a 1 is the effect of the resin percentage factor; • a 2 is the effect of the grain size factor; • a 12 is the interaction between the percentage of resin and the grain size.
• e is the gap.
Responses Y are classified based on relation to each experimental trial (Table 1).
The different combinations are formulated from epoxy resin percentages set at 20% and 40% representing, respectively, the low and high levels of factor 1 and the particle size of the different plant by-products ranging from 0.2 mm to 1 mm, representing factor 2. Table 2 provides information on the different formulations of the by-product-based abrasives obtained through the experiment.

Shaping of abrasives
The abrasives are shaped by the cold compression molding process. The first step consists in mixing the grains, and the resin previously weighed thanks to a mini mixer of 1000 W power for 2 minutes, thus making the constituents more homogeneous. Then, the mixture is filled into a hardened steel mold of internal dimensions 125 × 15×20 machined for the molding operation. The second step consists in compacting the mixture under a pressure of 17 MPa, for 30 minutes (polymerization time) using a hydraulic press with a cylinder of type E. RASSANT. The last step also called the curing phase, allows the abrasive wheels obtained to be maintained at 40°C for 2 hours in a Memmert UF110 type universal oven.

Physicochemical and thermal characterization • Porosity
The porosity (P) of the grinding wheels was performed using Equation 12 from ISO 5017 (Pinot 2015). Ten specimens in cubic shapes were used.
ρa: bulk density determined by the gravimetric method based on Archimedes' principle according to ASTM-D3800-99 (Sikame Tagne et al. 2020). ρr: real density of the abrasive obtained through the geometric method of the NF P 94,410-2 standard (Mansouri et al. 2007).
• Thermogravimetric analysis (TGA) of processed abrasives The test was carried out using a thermo balance STQ PT-1000 according to ISO 11,358:1997. The test allows the evaluation of the thermal stability of the abrasives. The 3 to 5 mg grinding wheel powders are introduced into a platinum crucible and heated in the furnace at a constant heating rate of 10°C/ min over a temperature range of 30°C to 600°C (Shukla, Kumar, and Srivastava 2006) under a nitrogen flow at a rate of 50 ml/min.
• Differential Scanning Calorimetry (DSC) of manufactured abrasives Differential scanning calorimetry was used to determine the maximum curing temperature of the processed abrasives. The measurements were carried out using the STQPT-1000 thermo balance. 5 mg of powder to be analyzed was taken from the abrasives of different by-products with 40% binder content and 1 mm grain size in the temperature range of 60 to 200°C with a heating/cooling rate of 10°C/min under nitrogen atmosphere (Achchaq et al. 2009).

Mechanical and tribological characterization • Leeb Hardness
The hardness of the samples was evaluated using a TH110 g drinking water hardness tester following the ASTM E140 standard. The principle is based on the dynamic rebound method (Asiri, Corkum, and El Naggar 2016). The samples used for the measurement are cubic with a 20 mm edge. Ten samples of each formulation are prepared and six measurements are performed on each of the six faces to obtain the average Leeb hardness values.
• Resilience testing Testing was performed on each abrasive formulation to determine impact fracture toughness using fracture energy. The device used is a Charpy pendulum hammer conforming to the ASTM D256 standard (William et al. 2022). The specimens are sized 4 × 3 × 27 mm 3 by the DIN 50,119 standard (Guillou, Guttmann, and Dumoulin 1981). The value of resilience is obtained by Equation 12.
where l, g, m, α, β, and S are the length of the pendulum (310 mm), the intensity of gravity, the mass of the pendulum, the angle of rising after breakage, the angle of the free rise of the pendulum, and the cross-sectional area of the test piece, respectively.
• Efficiency and wheel wear The efficiency of the grinding wheels was determined by evaluating the material removal rate (MRR) of a predefined material. The choice of the material depends on the field of application of the developed grinding wheel. The material chosen was a polymer for shoe soles with a hardness of Leeb 280 HL. The test device is a disc tribometer , where the different grinding wheels are mounted on the motor plate (7), and the polymer material is mounted on the jaw holder (6), as shown in Figure 2. Measurements of the mass loss of the grinding wheel and the polymer are carried out using a precision balance (10 −3 g). Each test lasts 10 seconds and is repeated three times in order to obtain the average material removal rates (MRR) given by equation (12) and the average wheel wear rates (WR). The contact pressure between the grinding wheel and the polymer of 400 mm 2 section is 0.125 MPa. The grinding wheels are driven at a speed of 1380 rpm.
m i is the initial mass before the test and m f is the final mass after the test expressed in grams. The coefficient of friction (µ) between the manufactured wheels and the selected test material can be determined during the wear test. It was obtained by the relation (13) Fr is the friction force obtained by the calibration relationship (Figure 2b) of the device. The calibration of the tribometer consists in establishing the correlation between the horizontal displacement of the pin plate (4) measured with a comparator and the imposed load determined with a precision digital dynamometer (10 −3 Kg). F N represents the normal load applied during the test.

Physical and mechanical characterization
The values of hardness and Young's modulus of Raphia fruit kernel obtained from equations (5) and Equation 8 are slightly lower than those of other by-products. The values are 100.67 MPa and 1.82 GPa respectively. Figure 3 shows the variation of hardness H and Young's Modulus E as a function of contact depth. An increasing evolution of hardness and Young's modulus with contact depth is observed. This behavior, although it is a plant product, is similar to the variation of hardness as a function of contact depth for titanium (TiW) and aluminum (Al) tungsten thin films deposited on a silicon (Si) substrate (Randall 2004). Table 3 compares the hardness and Young's modulus values of the raffia core with other plant by-products.
The hardness, Young's modulus and density of raffia fruit kernel are closer to the values of palm nut shells than cocos nut shells and fruit kernel of canarium schweinfurthii. Although the hardnesses of the by-products remain low compared to the hardnesses of some synthetic aluminum oxide abrasive grains that can reach a Knoop hardness of 20.3 GPa (Nadolny, Sutowski, and Herman 2015) they can be used in the realization of plant by-product abrasives (Njeugna et al. 2016) to abrade less hard materials. The production of abrasives, despite all the technological improvements, can be a severe source of pollution, requiring technical solutions to minimize environmental impacts (Mihăiescu et al. 2011), and bonded abrasives based on plant by-products are a particular solution to this concern. Thermogravimetric analysis Figure 4 shows the thermal stability of the raffia fruit kernel. The results reveal that the initial weight loss, attributed to moisture content, is equal to 9.22%. The first phase of degradation is linked to the thermal depolymerization of the hemicellulose and the cleavage of the glycosidic bonds of the cellulose, with a loss of mass ranging from 9.22% to 28.34%.
The TG and DTG curves show at the last phase of degradation related to the slow decomposition of lignin a higher mass loss of 47.56% between 352°C and 472°C. Owing to the complex structure of lignin (aromatic compound rings with various branches), its degradation occurs slowly within the whole temperature (Liu et al. 2004). These mass loss variations are close to plant-based fibrous materials reported by (Achchaq et al. 2009;Neto et al. 2015). It is also seen from the DSC curve that the Raphia fruit kernel has a significant heat release from 307°C onwards, accompanied by an exothermic peak at about 484°C, corresponding to thermal degradation.

Physical and thermal characterizations
Sixteen formulations of the abrasive wheels were made from the four mentioned by-products. Figure 5 shows some of the wheels developed from the experimental approach.
• Thermogravimetric analysis of grinding wheels The thermogravimetric analysis shows, the behavior of Coco EN 40-1, Palm EP 40-1, Canarium EC 40-1 and Raphia ER 40-1 abrasives. The general behavior is similar, with two significant degradation phases and a loss of moisture at the beginning of the test. Table 4 shows the summary data of the thermal behavior of the abrasives produced. This table, shows that the abrasives produced can easily withstand temperature gradients of the order of 200°C while retaining most of their properties. Although these results are globally appreciable, the raffia core abrasives show better thermal stability than the others with exothermic peaks up to 502°C. This high thermal stability is attributed to the presence of 40% resin content in the abrasive (Nagatani et al. 2019) but especially to the good thermal stability of the raffia core (Iwar et al. 2021).
The TG analysis of cresol-based benzoxazine abrasive binders shows a loss of half their mass between 240°C and 380°C (Jamrozik et al. 2020). These data from the literature are also close to the TG TG: Thermogravimetric analysis DTG: Differential thermal analysis DSC : Differential Scanning Calorimetry  results of EN 40-1, EP 40-1 and ER 40-1 abrasives. Heat resistance is a key parameter for abrasive materials, because friction stress can induce significant heating of the surfaces.
• Porosity of the abrasives made 2019) show that a high-porosity wheel has lower grinding temperatures and a higher material removal rate. It can be seen from Figure 6 that the abrasives of different combination by-products 20-1 have high porosities. This situation is due to the small quantity of resin of 20% and especially the abrasive grains of considerable size (1 mm). The porosity values are between 11.03 and 23.09% for all the wheels produced. These values are close to the porosities of grinding wheels based on abrasive grains made of aluminum oxide and vitrified binder (Mansouri et al. 2007). The technique used in processing modern abrasives to increase the porosity especially, of vitrified bonded abrasives is the use of pore inducers (Davis 2005).
It can be seen from Figure 6 that the porosity decreases as the binder increases. This is linked to the capacity of the binder to fill the voids by encrusting the grain particle. In addition, the larger abrasive grain size (1 mm) increases the porosity of the material due to the large number of voids created during molding.

Mechanical characteristics
• Leeb hardness (HL) of grinding wheels The Leeb hardness was carried out on all formulations. It can be seen that the hardness values increase with the binder content and the size of the particles. The HL hardness values are between 220 HL and 342 HL. The analysis of the results shows that the abrasives of different by-products produced have a high hardness when the binder content is 40% and with a particle size of 1 mm. This may be because when the abrasive grain sizes are close to their natural dimensions, they offer the best mechanical properties and also the mechanical properties of the resin, whose Young's modulus at room temperature can reach 3.74 GPa (Passilly et al. 2017). This behavior, on the one hand, is similar to abrasives based on periwinkle shells and polyester binder, indicating that increasing the concentration of polyester from 4 to 12% increases the hardness (Obot, Yawas, and Aku 2017). Table 5 compares the hardness of bonded abrasives made from 40-1 formulations with selected abrasives.
The studies on the hardness of the by-products are in line with the results of the bonded abrasives produced. With regard to Table 5, coconut-based abrasives have hardnesses comparable to abrasives of natural origin and certain friction materials.
• Resilience of grinding wheels Impact tests were carried out on all formulations. Table 6 provides information on the impact resistance values of manufactured bonded abrasives. The impact values of coconut-based abrasives range from 2.52 to 2.65 J/cm 2 , canarium core-based abrasives from 2.2 to 2.36 J/cm 2 , palm nut-based abrasives from 2.56 to 2.97 J/cm 2 and raffia core-based abrasives from 2.2 to 2.48 J/cm 2 . Regardless of the formulation, these values remain high compared to the breaking energy of epoxy resin measuring 100 to 300 j/m 2 ( Barrère and Dal Maso 1997). Those based on palm nuts show high impact resistance. It was found that the impact strength was lower for grinding wheels of identical formulations, when the hardness was increased.
From Table 6, we note that the abrasive grains of vegetable origin significantly increase the impact resistance of grinding wheels. The results show that the smaller base wheels are more resistant to impact. Some authors have concluded that a decrease in the resilience of abrasives can allow greater force to be applied and more material to be removed (Syreyshchikova and Yu Pimenov 2017).

Tribological characterization and effectiveness of abrasives
• Abrasive efficiency  The efficiency of the grinding wheel is characterized by its material removal rate (MRR). A commercial grinding wheel marked COM was subjected to the same test and under the same conditions in order to compare the different results. Figure 7 shows the material removal rate behavior and its evolution as a function of time. Looking at Figure 7(a), it can be seen that the material removal is higher by the 20-1 wheels for all types of abrasive grains. The MRR of the commercial wheel (COM) is 171.3 mg/s and is close to the values of the 20-1 wheels. The EN 20-1 coconut wheel has the highest efficiency, with a removal rate of 200.8 mg/s. From the full 2-level factorial design, the influence of resin percentage and particle size on the efficiency of the developed grinding wheels was analyzed. The trend of the effect of the factors is general for the by-product-based grinding wheels, as shown in Table 7. Figure 8 shows the influence of shaping factors on coconut-based grinding wheels. The average MRR on coconut-based grinding wheels is 154.33 mg/s. The effect of factor 1 is −2.18 mg/s for a 10% variation in binder percentage, and grain size is 22.27 mg/s for a 0.4 mm variation in abrasive grains.
It can be seen that the increase of 10% of the binder negatively influences the efficiency of the grinding wheels based on agro-industrial by-products. It would therefore be advisable to stabilize the binder content at the limit of less than 20%. However, the data in Table 7 show that it is possible to reduce it further to 10% for canarium core and raffia wheels as the effect of factor 1 are −11.15 and −11.90 respectively. On the other hand, increasing the abrasive grain size has a favorable influence on material removal. It seems evident that the optimal formulation of these grinding wheels is the 20-1 composition with 20% binder and 1 mm abrasive grain size. These compositions are strongly related to wheels with the highest porosity. The porosity of the bonded abrasives is, therefore, a parameter of the efficiency of the wheels (Davis 2005;Mansouri et al. 2007;Zhao et al. 2019).  In this study, the most effective agglomerated grinding wheel formulations are those with a 20% binder percentage and a particle size of 1 mm. Wheels can also be characterized by the wear rate WR, as shown in Table 8. The wear was determined during the material removal tests by measuring the mass variation at each test phase. Figure 9 shows the evolution of the friction coefficient obtained from the grinding wheels as a function of time.
The WR of the COM wheel is higher and is around 2.8 mg/s. This wheel also has the highest µ values of up to 0.51. The EN 20-1 and EP 20-1 wheels have almost a WR of around 0.7 mg/s, which is very low compared to benzoxazine and cresol-based abrasive materials (Jamrozik et al. 2020). The ER 20-1 wheel has a small WR of 0.1 mg/s and the lowest µ value, a with an average value of 0.24. The EC 20-1 grinding wheel has the largest WR of the developed materials with a value of 0.8 mg/s and an average friction coefficient of 0.35. In general, the friction increases during the first four seconds of the test. The wear values of the grinding wheels differ according to the type of grain of the by-products. This can be attributed to the porosity, friction temperature and intrinsic properties of the constituents.
The life of grinding wheels is often estimated from their wear (Mansouri et al. 2007). In context of this study, the grinding wheel ceases to be functional from the loss of half of its geometric configuration or dimension from the periphery to the center. In other words, once half of the initial mass is lost, it becomes difficult for the grinding wheel operator to shape the object. The life of the grinding wheels can be expressed in a number of phases corresponding to the duration of the wear test. Table 8 shows the values of the wear rates and the phases of operation of the wheels for the 20-1 combinations.
The wear of processed wheels is low when the average friction coefficient is reduced. Baky and Kamel (2019) observed this same abrasive wear phenomenon on jute-glass-carbon reinforced composites. Raffia-based wheels have the longest life and operating phases amounting to 124,723, corresponding to 346 hours, and a very low WR of 0.1 mg/s. This longer life can be attributed to the cohesion of the abrasive grains with the resin, its low wear rate and the good thermal stability of the  raffia core grains. The COM wheel has the lowest number of operating phases with a high RW of 2.8 mg/s. The wheels developed 20-1 and thus have good abrasive properties.

Conclusion
This work has identified four by-products that are sufficiently available locally, namely palm nut shells, Canarium fruit kernels, Coconut shells and Raphia Vinifera fruit kernels. On the other hand, there is no information in the literature on the mechanical characteristics of the raffia fruit kernel. This study contributed to determining raffia fruit kernel, hardness and Young's modulus by instrumented macro indentation method, which are 101 MPa and 1.82 GPa, respectively. These four by-products were processed into fine P80 and coarse P20 abrasive grains according to FEPA standard. The 2-level full factorial design method was adopted to analyze the influence of epoxy binder content and grit size on abrasive properties. Densities are lighter compared to the mineralbased grinding wheels. Increasing the abrasive grain size of the by-products and the binder content has a beneficial influence on the Leeb hardness, whose values range from 220 HL to 342 HL. Porosity is an attractive property as it is related to the efficiency of the grinding wheels. The efficiency of the wheels was evaluated by determining the material removal rate of a polymer material (Leeb hardness 280 HL) used to manufacture shoe soles. The EN 20-1, EC 20-1, EP 20-1, and ER 20-1 wheels have material removal rates of 200.8 mg/s, 165 mg/s, 160.3 mg/s and 183.4 mg/s, respectively, which are close to commercial wheels at 171.3 mg/s. These wheels are the ones with the best formulations in the experimental approach. Their wear rates are very low compared to commercial wheels, and their material working life is much higher. In sum, bonded abrasives made with 20-1 formulations can be used effectively in industrial applications for shaping shoe soles, rubber silent blocks, stripping operations, paint removal, and even in abrasive disc hullers. The microscopic and topographic analyses are necessary to further understand the behavior of grains of vegetable origin in the material removal phase.

Highlights
• Determination of the hardness and Young's modulus of raffia vinifera core; • Elaboration of abrasives based on 4 plant by-products; • Physico-chemical, thermal, tribological and mechanical characterization of abrasives; • Formulation 20-1 has the best tribological performance; • Areas of application (shoemaking industry, abrasive disc strippers, pickling).