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RESEARCH ARTICLE

Iddingsitisation of olivine and kaolinitisation of biotite in two contrasting tephra-derived soils along the Cameroon Volcanic Line (CVL)

Roger Kogge Enang https://orcid.org/0000-0002-1293-7795 A D , Florias Mees https://orcid.org/0000-0002-6190-8384 B , Bernard Palmer Kfuban Yerima A and Eric Van Ranst C
+ Author Affiliations
- Author Affiliations

A Soil Science Department, Faculty of Agronomy and Agricultural Sciences, University of Dschang, PO Box 222, Dschang, Cameroon.

B Department of Geology and Mineralogy, Royal Museum for Central Africa, Tervuren, Belgium.

C Department of Geology (WE13), Faculty of Sciences, Ghent University, Ghent, Belgium.

D Corresponding author. Email: enangrog@yahoo.com

Soil Research 59(3) 276-286 https://doi.org/10.1071/SR20155
Submitted: 2 June 2020  Accepted: 31 October 2020   Published: 2 December 2020

Abstract

Mineral transformations in soils are important processes in assessing pedogenesis. A micromorphological study, complemented by mineralogical and physicochemical analyses, was conducted for two contrasting soils developed on tephra of Mt. Manengouba, i.e. an Andosol and a Cambisol, in order to compare weathering trends based on olivine and biotite alteration. The contrasting character of the two soils is portrayed in their various properties, and is also observed in the field. The majority of the investigated soil properties proved to be effective in capturing differences between the two soils. Iddingsite, formed by pellicular alteration of olivine, occurs in both soils. Its presence is an inherited feature, as recorded by identical occurrences of affected olivine crystals as isolated grains in the groundmass of the soils and as phenocrysts in volcanic rock fragments within the Andosol profile. Kaolinitisation of biotite, producing parallel linear alteration patterns, is limited to the Cambisol and is attributed to pedogenic processes, recording a more advanced stage of weathering than for the Andosol profile. Kaolinitisation is thus more indicative in assessing pedogenesis compared with iddingsitisation in these soils.

Keywords: Andosols, biotite, Cambisols, micromorphology, Mt. Manengouba, olivine, pedogenesis, weathering.


References

Ahn JH, Peacor DR (1987) Kaolinitization of biotite: TEM data and implications for an alteration mechanism 1. The American Mineralogist 72, 353–356.

Baker I, Haggerty SE (1967) The alteration of olivine in basaltic and associated lavas part II: Intermediate and low temperature alteration. Contributions to Mineralogy and Petrology 16, 258–273.
The alteration of olivine in basaltic and associated lavas part II: Intermediate and low temperature alteration.Crossref | GoogleScholarGoogle Scholar |

Benyarku CA, Stoops G (2005) ‘Guidelines for preparation of rock and soil thin sections and polished sections. (Departament de Medi Ambient i Ciències del Sòl, Universitat de Lleida, Lleida).

Bisdom EBA, Stoops G, Delvigne J, Curmi P, Altemuller HJ (1982) Micromorphology of weathering biotite and its secondary products. Pédologie (Gent) 32, 225–252.

Blakemore LC, Searly PL, Daly BK (1981) Methods for chemical analysis of soils. NZ Soil Bureau Scientific Report 10A. Department of Scientific and Industrial Research, Lower Hutt, New Zealand.10.7931/DL1-SBSR-10A10.7931/DL1-SBSR-10A

Brindley GW (1980) Order-disorder in clay mineral structures. In ‘Crystal structures of clay minerals and their X-ray identification’. (Eds GW Brindley, G Brown) pp. 93–111. (Mineralogical Society: London: UK).

Bunch TE, Reid AM (1975) The nakhlites. Part I. Petrography and mineral chemistry. Meteoritics 10, 303–315.
The nakhlites. Part I. Petrography and mineral chemistry.Crossref | GoogleScholarGoogle Scholar |

Calhoun FG, Carlisle WW, Luna CZ (1972) Properties and genesis of selected Colombian Andosols. Soil Science Society of America Journal 36, 480–485.
Properties and genesis of selected Colombian Andosols.Crossref | GoogleScholarGoogle Scholar |

CDC Meteorological Service (2014) Climatic database. Cameroon Development Cooperation (CDC) Meteorological Service, Tiko.

Childs CW (1985) Towards understanding soil mineralogy: II. Notes on ferrihydrite. NZ Soil Bureau Laboratory Report CM7. Department of Scientific and Industrial Research, Lower Hutt, New Zealand.10.7931/DL1-LAB-CM0710.7931/DL1-LAB-CM07

Corti G, Sanjurjo MJF, Ugolini FC (1998) Randomly Interstratified Kaolinite-Smectite from Galicia (NW Spain): A New Procedure for Determination. Clays and Clay Minerals 46, 705–711.
Randomly Interstratified Kaolinite-Smectite from Galicia (NW Spain): A New Procedure for Determination.Crossref | GoogleScholarGoogle Scholar |

Delvaux B, Herbillon AJ, Vielvoye L (1989) Characterization of a weathering sequence of soils derived from volcanic ash in Cameroon. Taxonomic and agronomic implications. Geoderma 45, 375–388.
Characterization of a weathering sequence of soils derived from volcanic ash in Cameroon. Taxonomic and agronomic implications.Crossref | GoogleScholarGoogle Scholar |

Delvaux B, Herbillon AJ, Vielvoye L, Mestdagh MM (1990) Surface properties and clay mineralogy of hydrated halloysitic soil clays. II: Evidence for the presence of halloysite/smectite (H/Sm) mixed-layer clays. Clay Minerals 25, 141–160.
Surface properties and clay mineralogy of hydrated halloysitic soil clays. II: Evidence for the presence of halloysite/smectite (H/Sm) mixed-layer clays.Crossref | GoogleScholarGoogle Scholar |

Delvigne JE (1998) Atlas of micromorphology of mineral alteration and weathering. The Canadian Mineralogist Special Publication 3. ORSTOM and Mineralogical Association of Canada, Ottawa.

Delvigne JE, Bisdom EBA, Sleeman J, Stoops G (1979) Olivines, their pseudomorphs and secondary products. Pédologie (Gent) 29, 247–309.

Doube M (1989) Pedogenesis, classification and charge properties of the Bambouto soil sequence (West-Cameroon). Unpublished PhD thesis, Faculty of Sciences, State University of Ghent, Ghent.

Doube M, Van Ranst E (1984) La pédogenèse comparée et la valeur agricole des sols représentatifs des Hauts-Plateaux de l'Ouest Cameroun. Etude morphologique desprofils. MESRES, Centre Universitaire de Dschang, Cameroun.

Eggleton RA, Banfield JF (1985) The alteration of granitic biotite to chlorite. The American Mineralogist 70, 902–910.

Enang RK, Yerima PKB, Kome GK (2016) Soil physico-chemical properties and land suitability evaluation for maize (Zea mays), beans (Phaseolus vulgaris) and Irish potatoes (Solanum tuberosum) in tephra soils of the western slopes of mount Kupe (Cameroon). African Journal of Agricultural Research 11, 4571–4583.
Soil physico-chemical properties and land suitability evaluation for maize (Zea mays), beans (Phaseolus vulgaris) and Irish potatoes (Solanum tuberosum) in tephra soils of the western slopes of mount Kupe (Cameroon).Crossref | GoogleScholarGoogle Scholar |

Enang RK, Yerima PKB, Kome GK, Van Ranst E (2017) Effects of forest clearance and cultivation on bulk density variations and relationships with texture and organic matter in tephra soils of Mount Kupe (Cameroon). Communications in Soil Science and Plant Analysis 48, 2231–2245.
Effects of forest clearance and cultivation on bulk density variations and relationships with texture and organic matter in tephra soils of Mount Kupe (Cameroon).Crossref | GoogleScholarGoogle Scholar |

Enang RK, Yerima BPK, Kome GK, Van Ranst E (2018) Assessing the effectiveness of the Walkley-Black method for soil organic carbon determination in tephra soils of Cameroon. Communications in Soil Science and Plant Analysis 49, 2379–2386.
Assessing the effectiveness of the Walkley-Black method for soil organic carbon determination in tephra soils of Cameroon.Crossref | GoogleScholarGoogle Scholar |

Enang RK, Yerima BPK, Kome GK, Van Ranst E (2019) Short-range order minerals and dominant assessory properties controlling P sorption in tropical tephra soils of the Cameroon volcanic line (CVL). Open Journal of Soil Science 9, 113–139.
Short-range order minerals and dominant assessory properties controlling P sorption in tropical tephra soils of the Cameroon volcanic line (CVL).Crossref | GoogleScholarGoogle Scholar |

Enang RK, Yerima BPK, Kome GK, Van Ranst E (2020) Trace elements in tephra soils of mounts Kupe and Manengouba (Cameroon). Eurasian Soil Science 53, 595–606.
Trace elements in tephra soils of mounts Kupe and Manengouba (Cameroon).Crossref | GoogleScholarGoogle Scholar |

FAO (2006) ‘Guidelines for soil description, Fourth edition.’ (FAO: Rome).

Fitzpatrick EA (1984) ‘Micromorphology of soils.’ (Chapman and Hall: NY)

Goff FE (1977) Vesicle cylinders in vapor-differentiated basalt flows. PhD Thesis, University of California, Santa Cruz.

Hardjosoesastro RR (1956) Preliminary note on cristobalite in clay fractions of volcanic ashes. Journal of Soil Science 7, 185–188.
Preliminary note on cristobalite in clay fractions of volcanic ashes.Crossref | GoogleScholarGoogle Scholar |

Herbillon AJ (1986) Chemical estimation of weatherable minerals in the diagnostic horizons of low activity clay soils. In ‘Proceedings of the Eight International Soil Classification Workshop: Classification, Characterization and Utilization of Oxisols, Part 1.’ (Eds FH Beinroth, CU Camargo, H Eswaran) pp. 39–48. (EM-BRAPA: Rio de Janeiro).

International Organization for Standardization [ISO] (2002). ISO 90.60 14869–2:2002. Soil quality – dissolution for the determination of total element content – Part 2. Dissolution by alkaline fusion.

IUSS Working Group WRB (2015). World Reference Base for Soil Resources 2014, update 2015. International soil classification system for naming soils and creating legends for soil maps. World Soil Resources Reports No. 106. (FAO: Rome)

Jiang WT, Peacor DR (1991) Transmission electron microscopic study of the kaolinitization of muscovite. Clays and Clay Minerals 39, 1–3.
Transmission electron microscopic study of the kaolinitization of muscovite.Crossref | GoogleScholarGoogle Scholar |

Jiomeneck PST, Tematio P, Wilson MA, Yemefack M (2011) Andosolization of soils on a Strombolian cone at Mount Bambouto, Cameroon. Open Journal of Soil Science 1, 97–105.
Andosolization of soils on a Strombolian cone at Mount Bambouto, Cameroon.Crossref | GoogleScholarGoogle Scholar |

Kagou AD, Wandji P, Pouclet A, Vicat JP, Cheilletze A, Nkouathio DG, Alexandrov P, Tchoua FM (2001) Volcanological evolution of the Mount Manengouba (Cameroon line), new petrographical, geochemical, and geochronological data Comptes Rendus de l’Académie des Sciences - Series IIA - Earth and Planetary Science 333, 155–162.
Volcanological evolution of the Mount Manengouba (Cameroon line), new petrographical, geochemical, and geochronological dataCrossref | GoogleScholarGoogle Scholar |

Kendrick JL, Jamieson RA (2016) The fate of olivine in the lower crust: Pseudomorphs after olivine in coronitic metagabbro from the Grenville Orogen, Ontario. Lithos 260, 356–370.
The fate of olivine in the lower crust: Pseudomorphs after olivine in coronitic metagabbro from the Grenville Orogen, Ontario.Crossref | GoogleScholarGoogle Scholar |

Kome GK, Enang RK, Yerima PKB (2018) Knowledge and management of soil fertility by farmers in western Cameroon. Geoderma Regional 13, 43–51.
Knowledge and management of soil fertility by farmers in western Cameroon.Crossref | GoogleScholarGoogle Scholar |

Kuebler KE (2013) A comparison of the iddingsite alteration products in two terrestrial basalts and the Allan Hills 77005 Martian meteorite using Raman spectroscopy and electron microprobe analyses. Journal of Geophysical Research. Planets 118, 803–830.
A comparison of the iddingsite alteration products in two terrestrial basalts and the Allan Hills 77005 Martian meteorite using Raman spectroscopy and electron microprobe analyses.Crossref | GoogleScholarGoogle Scholar |

Kuebler KE, Wang A, Haskin LA, Jolliff BL (2003) A study of olivine alteration to iddingsite using Raman spectroscopy. Lunar and Planetary Science XXXIV, 1953

Le Maitre RW (2002) ‘Igneous rocks: A classification and glossary of terms. Recommendations of the International Union of Geological Sciences Sub Commission on the systematics of igneous rocks.’ (Cambridge University Press: Cambridge).

Lee MR, Tomkinson T, Hallis LJ, Mark DF (2015) Formation of iddingsite veins in the martian crust by centrepetal replacement of olivine: Evidence from the nakhlite meteorite Lafayette. Geochimica et Cosmochimica Acta 154, 49–65.
Formation of iddingsite veins in the martian crust by centrepetal replacement of olivine: Evidence from the nakhlite meteorite Lafayette.Crossref | GoogleScholarGoogle Scholar |

Manga VE, Suh CE, Agyingi CM, Shemang EM (2013) Mineralogy and geochemistry of soils developed along the slopes of Mt. Cameroon, West Africa. Journal of African Earth Sciences 81, 82–93.
Mineralogy and geochemistry of soils developed along the slopes of Mt. Cameroon, West Africa.Crossref | GoogleScholarGoogle Scholar |

Manga VE, Agyingi CM, Suh CE (2014) Trace element soil quality status of Mt. Cameroon soils. Advances in Geology 2014, 894103
Trace element soil quality status of Mt. Cameroon soils.Crossref | GoogleScholarGoogle Scholar |

Mateus ACC, Varajao AFDC, Oliveira FS, Schaefer CE (2018) Alteration of olivine in volcanic rocks from Trindade Island, South Atlantic. Applied Clay Science 160, 40–48.
Alteration of olivine in volcanic rocks from Trindade Island, South Atlantic.Crossref | GoogleScholarGoogle Scholar |

Mizota C, Aomine S (1975) Clay mineralogy of some volcanic ash soils in which cristobalite predominates. Soil Science and Plant Nutrition 21, 327–335.
Clay mineralogy of some volcanic ash soils in which cristobalite predominates.Crossref | GoogleScholarGoogle Scholar |

Njoyim EBT, Mvondo-Zé AD, Mofor NA, Onana AA (2016) Phosphorus adsorption isotherms in relation to soil characteristics of some selected volcanic affected soils of Foumbot in the West Region of Cameroon. International Journal of Soil Science 11, 19–28.
Phosphorus adsorption isotherms in relation to soil characteristics of some selected volcanic affected soils of Foumbot in the West Region of Cameroon.Crossref | GoogleScholarGoogle Scholar |

Parfitt RL, Wilson AD (1985) Estimation of allophane and halloysite in three sequences of volcanic soils. In ‘Volcanic soils, weathering and landscape relationships of soils on tephra and basalt’ Catena Supplement 7. (Eds E Fernandez-Caldos, DH Yaalon) pp. 1–8. (Schweizerbart Science Publishers: Stuttgart).

Pauwels JM, Van Ranst E, Verloo M, Mvondo Ze A (1992) ‘Manuel de laboratoire de pédologie. Méthodes d’analyses des sols et des plantes, équipement, gestion de stocks de verrerie et de produits chimiques’. (Publications Agricoles 28: Bruxelles).

Pouclet A, Kagou AD, Bardintzeff JM, Wandji P, Tagheu PC, Nkouathio D, Bellon H, Ruffet G (2014) The Mount Manengouba, a complex volcano of the Cameroon Line: Volcanic history, petrological and geochemical features. Journal of African Earth Sciences 97, 297–321.
The Mount Manengouba, a complex volcano of the Cameroon Line: Volcanic history, petrological and geochemical features.Crossref | GoogleScholarGoogle Scholar |

Rebertus RA, Weed SB, Buol SW (1986) Transformations of biotite to kaolinite during saprolite-soil weathering. Soil Science Society of America Journal 50, 810–819.
Transformations of biotite to kaolinite during saprolite-soil weathering.Crossref | GoogleScholarGoogle Scholar |

Ross CS, Shannon EV (1925) The origin, occurrence, composition and physical properties of the mineral Iddingsite. Proceedings of the United States National Museum 67, 1–19.
The origin, occurrence, composition and physical properties of the mineral Iddingsite.Crossref | GoogleScholarGoogle Scholar |

Smith KL, Milnes AR, Eggleton R (1987) Weathering of basalt: formation of iddingsite. Clays and Clay Minerals 35, 418–428.
Weathering of basalt: formation of iddingsite.Crossref | GoogleScholarGoogle Scholar |

Soil Survey Staff (1996) Soil Survey Laboratory Methods Manual. Procedures for collecting soil samples and methods of analysis for soil survey. Soil Survey Investigation Report No. 42, version 3.0, USDA, Washington DC.

Stoch L, Sikora W (1976) Transformations of micas in the process of kaolinitization of granites and gneisses. Clays and Clay Minerals 24, 156–162.
Transformations of micas in the process of kaolinitization of granites and gneisses.Crossref | GoogleScholarGoogle Scholar |

Stoops G (2003) ‘Guidelines for analysis and description of soil and regolith thin sections.’ (Soil Science Society of America Inc: Madison).

Stoops G, Mees F (2018) Groundmass composition and fabric. In ‘Interpretation of micromorphological features of soils and regoliths.’ 2nd edn. (Eds G Stoops, V Marcelino, F Mees) pp. 73–125. (Elsevier: Amsterdam).

Stoops G, Sedov S, Shoba S (2018) Regoliths and soils on volcanic ash. In ‘Interpretation of micromorphological features of soils and regoliths.’ 2nd edn. (Eds G Stoops, V Marcelino, F Mees) pp. 721–751. (Elsevier: Amsterdam).

Suga H, Suzuki K, Yamaguchi A, Usui T, Takahashi Y (2018) Characterization of fluid flow path regarding iddingsite formation in the Martian meteorite Yamato 000593 based on the 3D Fe chemical species imaging. The Ninth symposium on Polar Science/Ordinary sessions: [OA] Antarctic meteorites/Hayabusa. National Institute of Polar Research. Tokyo, Japan.

Swindle TD, Treiman HA, Lindstrom DJ, Burklandi MK, Cohen BA, Grier JA, Li BK, Olson EK (2000) Noble gases in iddingsite from the Lafayette meteorite: Evidence for liquid water on Mars in the last few hundred million years. Meteoritics & Planetary Science 35, 107–115.
Noble gases in iddingsite from the Lafayette meteorite: Evidence for liquid water on Mars in the last few hundred million years.Crossref | GoogleScholarGoogle Scholar |

Tematio P, Kengni L, Bitom D, Hodson ME, Fopoussi JC (2004) Soils and their distribution on Bambouto volcanic mountain, West Cameroon highland, Central Africa. Journal of African Earth Sciences 39, 447–457.
Soils and their distribution on Bambouto volcanic mountain, West Cameroon highland, Central Africa.Crossref | GoogleScholarGoogle Scholar |

Tematio P, Fritsch E, Hodson ME, Lucas Y, Bitom D, Bilong P (2009) Mineral and geochemical characterization of a lepticaluandic soil and a thaptoaluandic-ferralsol developed on trachytes in Mount Bambouto (Cameroon volcanic line). Geoderma 152, 314–323.
Mineral and geochemical characterization of a lepticaluandic soil and a thaptoaluandic-ferralsol developed on trachytes in Mount Bambouto (Cameroon volcanic line).Crossref | GoogleScholarGoogle Scholar |

Tematio P, Tsafack EI, Kengni L (2011) Effects of tillage, fallow and burning on selected properties and fertility status of Andosols in the Mounts Bambouto, West Cameroon. Agricultural Sciences 2, 334–340.
Effects of tillage, fallow and burning on selected properties and fertility status of Andosols in the Mounts Bambouto, West Cameroon.Crossref | GoogleScholarGoogle Scholar |

Temgoua E, Djoukouo J, Likeng JDH, Tematio P (2014) Structural stability of Andosols and Andic Ferralsols from Mount Bambouto, West Cameroon highlands. Cameroon Journal of Experimental Biology 10, 26–34.
Structural stability of Andosols and Andic Ferralsols from Mount Bambouto, West Cameroon highlands.Crossref | GoogleScholarGoogle Scholar |

Tening AS, Foba-Tendo JN, Yakum-Ntaw SY, Tchuenteu F (2013) Phosphorus fixing capacity of a volcanic soil on the slope of Mount Cameroon. Agriculture and Biology Journal of North America 4, 166–174.
Phosphorus fixing capacity of a volcanic soil on the slope of Mount Cameroon.Crossref | GoogleScholarGoogle Scholar |

Tsozué D, Bitom D, Nghonda JP (2011) Andosols of the eastern slope of the Bambouto Mountains (West Cameroon): general characteristics, impact on human activities and environmental risks. Syllabus Review Science Series 2, 57–68.

Van Ranst E, Hof J, Kips PhA, Awah ET, Zambo J (1989) Volcanic soils of the lower south eastern and eastern slopes of Mount Cameroon (West Africa). Technical Report, University Centre of Dschang, Soil Science Department, Dschang, Cameroon: 172 pp.

Van Ranst E, Doube M, Mees F, Dumon M, Ye L, Delvaux B (2019a) Andosolization of ferralitic soils in the Bambouto Mountains, West Cameroon. Geoderma 340, 81–93.
Andosolization of ferralitic soils in the Bambouto Mountains, West Cameroon.Crossref | GoogleScholarGoogle Scholar |

Van Ranst E, Mees F, De Grave E, Ye L, Cornelis JT, Delvaux B (2019b) Impact of Andosolization on pedogenic Fe oxides in ferralitic soils. Geoderma 347, 244–251.
Impact of Andosolization on pedogenic Fe oxides in ferralitic soils.Crossref | GoogleScholarGoogle Scholar |

van Reeuwijk LP (2002) ‘Procedures for soil analyses.’ Technical Paper 9, 6th edn. (ISRIC: Wageningen)