Microwave-Promoted Hydroxycarbonylation in Water Using Gaseous Carbon Monoxide and Pre-Pressurized Reaction Vessels

 

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Abstract

The microwave-promoted hydroxycarbonylation of aryl iodides using reaction vessels pre-pressurized with CO is reported. Reactions are performed using simple palladium salts with loadings of either 0.01 mol% or 1 mol%.

References and Notes

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Specially designed reactors have been used for gas phase catalysis under microwave irradiation. See ref. 7 and references therein.

Synthos 3000 available from Anton Paar GmbH (www.anton-paar.com).