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Synthesis 1986; 1986(11): 956-958
DOI: 10.1055/s-1986-31836
DOI: 10.1055/s-1986-31836
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Eine neue Methode zur Synthese 3-substituierter Indole durch ipso-Substitution
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Publication History
Publication Date:
20 August 2002 (online)
An New Method for the Synthesis of 3-Substituted Indoles by ipso-Substitution Acylation of 3-(trimethylsilyl)-indole 1a with acylhalides 2 affords 3-acylindoles 4. 3-(Trimethylsilyl)-indoles 1a, b react with Michael-acceptors 5 and 8 in presence of Lewis acids to yield the 3-substituted indoles 6, 9, and 10.