A New Method for the Synthesis of Iminoquinones via DMP-Mediated Oxidative Reaction

 

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Abstract

Iminoquinones were synthesized by oxidation of primary and secondary amines with hypervalent iodine reagent Dess-Martin periodinane in average to good yields, and possible mechanisms were postulated. This methodology is convenient to establish a library of diversified iminoquinone compounds and has great significance for their potential application in the field of pharmaceuticals.

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CCDC 643540 contains supplementary crystallographic data for compound 2a; data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.