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Synthesis 1989; 1989(2): 97-101
DOI: 10.1055/s-1989-27162
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Phosphoranaloge von Aminosäuren II1 . Synthese von α-Aminophosphonsäuren und α-Aminophosphinsäuren, ausgehend von den entsprechenden N-Acylimino-Derivaten

Thomas Schrader* , Wolfgang Steglich
  • *Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300 Bonn 1, Federal Republic of Germany
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Publication Date:
17 September 2002 (online)

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Synthesis of α-Amino Phosphonic Acids and α-Amino Phosphinic Acids via the Corresponding N-Acylimino Derivatives Acyliminomethylphosphonic and acyliminomethylphosphinic esters, usually formed in situ from the corresponding acylamino(bromo)methyl compounds, react with higher order mixed cuprates to yield, after hydrolysis, C-substituted aminomethylphosphonic acids and aminomethylphosphinic acids, respectively.

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