Issue 17, 1994

Bartanol and bartallol, novel macrodiolides from Cytospora sp. ATCC 20502

Abstract

Two new macrodiolides, bartanol 10 and bartallol 11 have been isolated from a Cytospora sp. and their structures established by a detailed study of their high field 1H and 13C NMR spectra. Unlike the other 14-membered ring macrodiolides isolated from this source, bartanol and bartallol have a novel rearranged 13-membered macrocyclic ring. The conformations of the macrocyclic ring have been deduced from the analyses of difference NOE spectra and 1H–1H coupling constants.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1994, 2493-2497

Bartanol and bartallol, novel macrodiolides from Cytospora sp. ATCC 20502

K. Hanson, J. A. O'Neill, T. J. Simpson and C. L. Willis, J. Chem. Soc., Perkin Trans. 1, 1994, 2493 DOI: 10.1039/P19940002493

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