The highly asymmetric induction imparted by the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] is exploited in the preparation of homochiral (R)- and (S)-α-pentylsuccinates. Their application in the synthesis of (–)-actinonin and (–)-epi-actinonin is described.
G. Bashiardes, G. J. Bodwell and S. G. Davies, J. Chem. Soc., Perkin Trans. 1, 1993, 459 DOI: 10.1039/P19930000459
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