Issue 10, 1991
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Microbial oxidation of 7endo-methylbicyclo[3.2.0]hept-2-en-6-one, 7,7-dimethylbicyclo[3.2.0]hept-2-en-6-one and 2exo-bromo-3endo-hydroxy-7,7-dimethylbicyclo[3.2.0]heptan-6-one using Acinetobacter NCIMB 9871

Andrew J. Carnell,   Stanley M. Roberts,   Vladimir Sik  and  Andrew J. Willetts  

Abstract

A bio-Baeyer–Villiger reaction using Acinetobacter NCIMB 9871 and the bicycloheptanone 2 provided the corresponding substituted oxabicyclooctanones 6 and 7. Similarly the ketones 3 and 9 furnished the lactones 8 and 10 respectively: the lactones 6, 7 and 10 were obtained in states of high optical purity.

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Article information

DOI
https://doi.org/10.1039/P19910002385
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1991, 2385-2389

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Microbial oxidation of 7endo-methylbicyclo[3.2.0]hept-2-en-6-one, 7,7-dimethylbicyclo[3.2.0]hept-2-en-6-one and 2exo-bromo-3endo-hydroxy-7,7-dimethylbicyclo[3.2.0]heptan-6-one using Acinetobacter NCIMB 9871

A. J. Carnell, S. M. Roberts, V. Sik and A. J. Willetts, J. Chem. Soc., Perkin Trans. 1, 1991, 2385 DOI: 10.1039/P19910002385

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