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The acid-catalysed rearrangement of 2,5-dialkyl-2,5-dioxy-2,5-dihydrofurans (9) and (15) are key steps common to two alternative approaches to the dispiroacetal ring system of salinomycin and related polyether antibiotics.
P. Kocieński, Y. Fall and R. Whitby, J. Chem. Soc., Perkin Trans. 1, 1989, 841 DOI: 10.1039/P19890000841
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