Issue 0, 1987
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Oxidation of N-acyl-pyrrolidines and -piperidines with lron(II)-hydrogen peroxide and an iron complex-molecular oxygen

Satoru Murata,   Masahiro Miura  and  Masakatsu Nomura  

Abstract

The reactions of N-acyl-pyrrolidines (1a–c) and -piperidines (1d–f) with FeII-hydrogen peroxide in aqueous 95% acetonitrile gave the corresponding pyrrolidin-2-ones (2a–c) and piperidin-2-ones (2d–f). The lactams (2a–f) were also the products in the oxidation of (1a–f) with molecular oxygen in the presence of an iron complex, either [FeIIFeIII2O(OAc)6(py)3] or [{Fe(salen)}2O], in aqueous 90% pyridine.

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Article information

DOI
https://doi.org/10.1039/P19870001259
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1987, 1259-1262

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Oxidation of N-acyl-pyrrolidines and -piperidines with lron(II)-hydrogen peroxide and an iron complex-molecular oxygen

S. Murata, M. Miura and M. Nomura, J. Chem. Soc., Perkin Trans. 1, 1987, 1259 DOI: 10.1039/P19870001259

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