Issue 0, 1986
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

The invention of new radical chain reactions. Part 12. Improved methods for the addition of carbon radicals to substituted allylic groups

Derek H. R. Barton  and  David Crich  

Abstract

Reagents for the allylation of carbon radicals derived from the esters (mixed anydrides) of N-hydroxy-2-thiopyridone have been investigated. Because of competition between the background reaction of decarboxylative rearrangement and the desired allylation process, conventional allylation reagents give moderate yields of the desired adducts. Improved yields are secured if the β-position bears an electron withdrawing group. A concerted addition and elimination process can be postulated.

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Article information

DOI
https://doi.org/10.1039/P19860001613
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1986, 1613-1619

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The invention of new radical chain reactions. Part 12. Improved methods for the addition of carbon radicals to substituted allylic groups

D. H. R. Barton and D. Crich, J. Chem. Soc., Perkin Trans. 1, 1986, 1613 DOI: 10.1039/P19860001613

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