Issue 0, 1986
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Tetrakis-sulphoxides: a new type of phase-transfer catalyst for nucleophilic displacements and alkylations

Hisashi Fujihara,   Koji Imaoka,   Naomichi Furukawa  and  Shigeru Oae  

Abstract

Tetrakis(alkylsulphinylmethyl)methanes have been shown to serve as good phase-transfer catalysts which accelerate SN2 type displacements of octyl bromide with various nucleophiles (thiocyanate, cyanide, phenoxide, and thiolate) in solid–liquid two-phase systems. Alkylation of phenylacetonitrile with alkyl halides has also been carried out in liquid–liquid two-phase systems in the presence of the above sulphoxides to afford the corresponding mono-alkylated products in high yields.

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Article information

DOI
https://doi.org/10.1039/P19860000333
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1986, 333-336

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Tetrakis-sulphoxides: a new type of phase-transfer catalyst for nucleophilic displacements and alkylations

H. Fujihara, K. Imaoka, N. Furukawa and S. Oae, J. Chem. Soc., Perkin Trans. 1, 1986, 333 DOI: 10.1039/P19860000333

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