Issue 0, 1985
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Pentavalent organobismuth reagents. Part 2. The phenylation of phenols

Derek H. R. Barton,   Neerja Yadav Bhatnagar,   Jean-Claude Blazejewski,   Brigitte Charpiot,   Jean-Pierre Finet,   David J. Lester,   William B. Motherwell,   M. Teresa Barros Papoula  and  Stephen P. Stanforth  

Abstract

The phenylation of a variety of phenols by pentavalent bismuth reagents under neutral, acid and basic conditions has been investigated. Under basic conditions well defined pentavalent intermediates have been isolated and fully characterised. Their decomposition gives only ortho-C-phenylation (except in the case of a p-nitrophenol derivative). O-Phenylation is seen under neutral or acidic conditions. Another mechanism is proposed to explain this reaction with no pentavalent bismuth intermediate.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/P19850002657
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1985, 2657-2665

Permissions

Request permissions

Pentavalent organobismuth reagents. Part 2. The phenylation of phenols

D. H. R. Barton, N. Y. Bhatnagar, J. Blazejewski, B. Charpiot, J. Finet, D. J. Lester, W. B. Motherwell, M. T. B. Papoula and S. P. Stanforth, J. Chem. Soc., Perkin Trans. 1, 1985, 2657 DOI: 10.1039/P19850002657

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements