Issue 0, 1985
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Investigation of new chiral 1,3-oxazolidine-2-thiones: analytical separation and optical resolution of racemic carboxylic acids and amino acids

Yoshimitsu Nagao,   Toshio Kumagai,   Shozo Yamada,   Eiichi Fujita,   Yoshinori Inoue,   Yunosuke Nagase,   Sakae Aoyagi  and  Takao Abe  

Abstract

New chiral five-membered heterocycles, (4S)-(4) and (4R)-4-ethyl-1,3-oxazolidine-2-thione (5), (4S)-4-isopropyl-1,3-oxazolidine-2-thione (6), and (4R,5S)-4-methyl-5-phenyl-1,3-oxazolidine-2-thione [(4R,5S)-MPOT](7) have been developed. Among these heterocycles, (4R,5S)-MPOT (7) proved to be an excellent chiral reagent for analytical and efficient separation of racemic products from transformations of chiral carboxylic acids and amino acids.

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Article information

DOI
https://doi.org/10.1039/P19850002361
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1985, 2361-2367

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Investigation of new chiral 1,3-oxazolidine-2-thiones: analytical separation and optical resolution of racemic carboxylic acids and amino acids

Y. Nagao, T. Kumagai, S. Yamada, E. Fujita, Y. Inoue, Y. Nagase, S. Aoyagi and T. Abe, J. Chem. Soc., Perkin Trans. 1, 1985, 2361 DOI: 10.1039/P19850002361

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