Issue 0, 1985
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Spirodienones. Part 5. The synthesis and reactions of N-sulphonylcyclohexadienimines

Ian G. C. Coutts,   Nicholas J. Culbert,   Mark Edwards,   John A. Hadfield,   Donald R. Musto,   Vasilios H. Pavlidis  and  David J. Richards  

Abstract

The anodic or chemical oxidation of para-substituted sulphonanilides gives 4,4-disubstituted N-sulphonylcyclohexadienimines, which, from appropriately substituted anilines, may be spirocyclic. The scope and limitations of the synthesis are described, and a mechanism proposed. The selective hydrolysis of the dienimines to the corresponding dienones provides a convenient route to the latter compounds. The reaction of some of the dienimines with dienes is discussed.

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Article information

DOI
https://doi.org/10.1039/P19850001829
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1985, 1829-1836

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Spirodienones. Part 5. The synthesis and reactions of N-sulphonylcyclohexadienimines

I. G. C. Coutts, N. J. Culbert, M. Edwards, J. A. Hadfield, D. R. Musto, V. H. Pavlidis and D. J. Richards, J. Chem. Soc., Perkin Trans. 1, 1985, 1829 DOI: 10.1039/P19850001829

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