Issue 0, 1979
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Di-π-methane rearrangement of 4-heteroaryl-1,4(or 3,4)-dihydropyrimidines

Roland E. van der Stoel  and  Henk C. van der Plas  

Abstract

Several 4-R-1,4(or 3,4)-dihydropyrimidines (R = 2- or 3-thienyl, 2-furyl, 1-methylpyrrol-2-yl, and 3-pyridyl), containing heteroaryl vinyl methane units were shown to undergo photochemical rearrangement into 5-R-1,2(or 2,3)-dihydropyrimidines. These compounds were oxidized to yield 5-heteroarylpyrimidines. The chemical yields of the photorearrangement were found to be strongly dependent on the nature of the heteroaryl group.

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Article information

DOI
https://doi.org/10.1039/P19790002393
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1979, 2393-2396

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Di-π-methane rearrangement of 4-heteroaryl-1,4(or 3,4)-dihydropyrimidines

R. E. van der Stoel and H. C. van der Plas, J. Chem. Soc., Perkin Trans. 1, 1979, 2393 DOI: 10.1039/P19790002393

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