Issue 8, 1977
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Some reactions of unsaturated sulphur–nitrogen heterocycles with nucleophilic substrates

Derek H. R. Barton  and  William A. Bubb  

Abstract

The reactivity of unsaturated sulphur–nitrogen heterocycles towards a variety of nucleophilic organic substrates has been studied. Tetrasulphur tetranitride (S4N4) is a relatively poor electrophile, but thiotrithiazyl chloride (S4N3Cl) and especially trithiazyl trichloride (S3N3Cl3) react readily with electron-rich molecules. However, the diversity of mechanistic pathways followed by these reagents imposes limitations on their synthetic utility.

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Article information

DOI
https://doi.org/10.1039/P19770000916
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1977, 916-923

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Some reactions of unsaturated sulphur–nitrogen heterocycles with nucleophilic substrates

D. H. R. Barton and W. A. Bubb, J. Chem. Soc., Perkin Trans. 1, 1977, 916 DOI: 10.1039/P19770000916

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