Issue 10, 1995

The M(dddt)2 family of conducting complexes: [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K

Abstract

The first stable molecular metal, [Ni(dddt)2]3(AuBr2)2, among the M(dddt)2 family of conducting charge-transfer salts has been prepared and its crystal structure has been solved by X-ray analysis. The origin of the metallic conductivity of [Ni(dddt)2]3(AuBr2)2 as well as the stability of this salt with respect to metal-to-insulator transitions is explained on the basis of tight-binding band structure calculations.

Article information

Article type
Paper

J. Mater. Chem., 1995,5, 1633-1638

The M(dddt)2 family of conducting complexes: [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K

L. A. Kushch, V. V. Gritsenko, L. I. Buravov, A. G. Khomenko, G. V. Shilov, O. A. Dyachenko, V. A. Merzhanov, E. B. Yagubskii, R. Rousseau and E. Canadell, J. Mater. Chem., 1995, 5, 1633 DOI: 10.1039/JM9950501633

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