Issue 0, 1968
From the journal:

Journal of the Chemical Society C: Organic

Studies on the reaction of benzoyl peroxide with NN-dialkyl aromatic amines and other related compounds. Part II. Reactions of some primary and secondary amines

R. B. Roy  and  G. A. Swan  

Abstract

The reaction of benzoyl peroxide with N-methylaniline and N-ethylaniline yields NN′-dimethylhydrazobenzene and NN′-diethylhydrazobenzene, respectively, in addition to previously reported products. The yields of 2-(N-alkylbenzamido) phenols can be increased by carrying out the reaction in benzene in the presence of aqueous sodium hydroxide; this reaction provides a preparative method for the o-hydroxylation of N-alkylanilines. This modification also enables o-benzamidophenols to be obtained from primary aromatic amines.

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Article information

DOI
https://doi.org/10.1039/J39680000080
Article type
Paper

J. Chem. Soc. C, 1968, 80-83

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Studies on the reaction of benzoyl peroxide with NN-dialkyl aromatic amines and other related compounds. Part II. Reactions of some primary and secondary amines

R. B. Roy and G. A. Swan, J. Chem. Soc. C, 1968, 80 DOI: 10.1039/J39680000080

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