SCHEDULED MAINTENANCE
Ferricyanide oxidation of reticuline affords the aporphine, isoboldine, in 0·5% yield. The bromo-analogue of reticuline gives an improved yield (2·5%) of isoboldine, the bromine atom being eliminated during the oxidative coupling reaction. Methylation of the isoboldine with diazomethane yields glaucine.
A. H. Jackson and J. A. Martin, J. Chem. Soc. C, 1966, 2061 DOI: 10.1039/J39660002061
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