Issue 0, 1970
From the journal:

Journal of the Chemical Society B: Physical Organic

Electron spin resonance studies. Part XXV. Reactions of the sulphate radical anion with organic compounds

R. O. C. Norman,   P. M. Storey  and  P. R. West  

Abstract

E.s.r. spectra are reported for the radicals obtained by the oxidation of a variety of organic compounds by the titanium(III)–persulphate redox system. Evidence is obtained that the sulphate radical anion is formed throughout the pH range employed (1–10·5) and that it can react with organic compounds in at least three ways: by abstracting a hydrogen atom from saturated carbon, by adding to unsaturated or aromatic carbon, and by removing one electron from carboxylate anions and from certain neutral molecules. It displays a marked degree of selectivity in its addition reactions and it behaves differently from the hydroxyl radical in several respects.

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Article information

DOI
https://doi.org/10.1039/J29700001087
Article type
Paper

J. Chem. Soc. B, 1970, 1087-1095

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Electron spin resonance studies. Part XXV. Reactions of the sulphate radical anion with organic compounds

R. O. C. Norman, P. M. Storey and P. R. West, J. Chem. Soc. B, 1970, 1087 DOI: 10.1039/J29700001087

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