Issue 0, 1968
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Thiocarbonyl and carbon disulphide complexes of ruthenium

J. D. Gilbert,   M. C. Baird  and  G. Wilkinson  

Abstract

The interaction of tris(triphenylphosphine)dichlororuthenium(II) with carbon disulphide leads to two complexes of the respective formulae [RuCl2(CS)(PPh3)2]2 and [RhCl(CS2)(PPh3)3]Cl; the former has a thiocarbonyl group and the latter a π-carbon disulphido-group. The halogen bridges in the thiocarbonyl complex can be cleaved by carbon monoxide, pyridine (py),2,2′-bipyridyl (bipy), or 1,10-phenanthroline (phen) to give octahedral ruthenium(II) complexes, e.g., RuCl2(CS)(CO)(PPh3)2. From the reaction in methanol solution, non-sulphur-containing complexes, e.g., [Ru2Cl2(bipy)2(PPh3)4]Cl2 are obtained. The new complexes are characterised by analysis and infrared spectroscopic studies.

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Article information

DOI
https://doi.org/10.1039/J19680002198
Article type
Paper

J. Chem. Soc. A, 1968, 2198-2201

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Thiocarbonyl and carbon disulphide complexes of ruthenium

J. D. Gilbert, M. C. Baird and G. Wilkinson, J. Chem. Soc. A, 1968, 2198 DOI: 10.1039/J19680002198

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