Issue 0, 1966
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Molecular-orbital theory of organometallic compounds. Part VI. Substitution reactions of some tricarbonylarenechromiums

David A. Brown  and  J. R. Raju  

Abstract

The kinetics of the nucleophilic substitution of some tricarbonylhalogenobenzenechromiums by methoxide ion in methanol are reported. The reaction is shown to be a typical SN2 displacement and the enhanced reactivity of the π-complex relative to the free halogenobenzene is in accord with previous theoretical predictions. Recent studies of electrophilic substitution of these complexes are also discussed.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/J19660000040
Article type
Paper

J. Chem. Soc. A, 1966, 40-43

Permissions

Request permissions

Molecular-orbital theory of organometallic compounds. Part VI. Substitution reactions of some tricarbonylarenechromiums

D. A. Brown and J. R. Raju, J. Chem. Soc. A, 1966, 40 DOI: 10.1039/J19660000040

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements