The 14N n.m.r. spectra of a variety of sulphur–nitrogen heterocycles and metal–sulphur–nitrogen complexes have been recorded and the observed shifts correlated with bonding type. The utility of 14N n.m.r. spectroscopy as a mechanistic tool in sulphur–nitrogen chemistry is illustrated for reactions in liquid ammonia.
I. P. Parkin, J. D. Woollins and P. S. Belton, J. Chem. Soc., Dalton Trans., 1990, 511 DOI: 10.1039/DT9900000511
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