Issue 7, 1988
From the journal:

Journal of the Chemical Society, Dalton Transactions

Preparation and nuclear magnetic resonance spectroscopy of [Ag2{µ-CH2(PPh2)2}3][O3SCF3]2, a disilver(I) complex with three bridging CH2(PPh2)2 ligands

Dagmar Obendorf,   Michael Probst,   Paul Peringer,   Heinz Falk  and  Norbert Müller  

Abstract

[Ag2(µ-dppm)3][O3SCF3]2[dppm = bis(diphenylphosphino)methane] has been prepared and characterized by 31P n.m.r. spectroscopy. Variable-temperature n.m.r. studies revealed that the Ag–P bonds are kinetically stable on the n.m.r. time-scale below 233 K. At ambient temperature there is intermolecular ligand exchange whereas at intermediate temperatures intramolecular inter-metal exchange of the phosphorus atoms of the dppm ligands occurs.

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Article information

DOI
https://doi.org/10.1039/DT9880001709
Article type
Paper

J. Chem. Soc., Dalton Trans., 1988, 1709-1711

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Preparation and nuclear magnetic resonance spectroscopy of [Ag2{µ-CH2(PPh2)2}3][O3SCF3]2, a disilver(I) complex with three bridging CH2(PPh2)2 ligands

D. Obendorf, M. Probst, P. Peringer, H. Falk and N. Müller, J. Chem. Soc., Dalton Trans., 1988, 1709 DOI: 10.1039/DT9880001709

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