Issue 10, 1980
From the journal:

Journal of the Chemical Society, Dalton Transactions

Investigation into aroylhydrazones as chelating agents. Synthesis and structural characterization of a tin(IV) complex with 2,6-diacetylpyridine bis(salicyloylhydrazone)

Corrado Pelizzi  and  Giancarlo Pelizzi  

Abstract

2,6-Diacetylpyridine bis(salicyloylhydrazone)(H2daps) has been synthesized and its co-ordinating properties have been investigated in the complex [SnPrn2(daps)] by means of spectroscopic (i.r. and u.v.) and X-ray diffractometric techniques. Crystals of the compound are orthorhombic, with a= 18.332(10), b= 17.187(11), c= 9.161(5)Å; Z= 4, space group P212121. A total of 1 936 observed reflections have been measured by single-crystal diffractometry and refined by full-matrix least squares to R 0.0402. The quinquedentate behaviour and the near planarity of the organic ligand favours a pentagonal-bipyramidal arrangement around tin with the two propyl groups occupying the axial sites.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9800001970
Article type
Paper

J. Chem. Soc., Dalton Trans., 1980, 1970-1973

Permissions

Request permissions

Investigation into aroylhydrazones as chelating agents. Synthesis and structural characterization of a tin(IV) complex with 2,6-diacetylpyridine bis(salicyloylhydrazone)

C. Pelizzi and G. Pelizzi, J. Chem. Soc., Dalton Trans., 1980, 1970 DOI: 10.1039/DT9800001970

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements