Volume 47, 1969
From the journal:

Discussions of the Faraday Society

Some bonding questions prompted by studies of the fluxional molecule triscyclopentadienylnitrosylmolybdenum

F. A. Cotton  

Abstract

The compound (C5H5)3MoNO has been prepared. Its proton magnetic resonance spectrum in solution has been studied as a function of temperature down to –110°. The crystal structure has been determined with relatively high precision at 22°. The combined results of these studies lead to some new observations concerning the manner in which cyclopentadienyl rings may be bonded to metal atoms. Specific conclusions are (a) that a trihapto (i.e., π-allylic) form of bonding is not a real possibility, and (b) unsymmetrical relationships of ring to metal, which cannot be readily described in terms of any simple limiting structure, are possible under certain conditions.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DF9694700079
Article type
Paper

Discuss. Faraday Soc., 1969,47, 79-83

Permissions

Request permissions

Some bonding questions prompted by studies of the fluxional molecule triscyclopentadienylnitrosylmolybdenum

F. A. Cotton, Discuss. Faraday Soc., 1969, 47, 79 DOI: 10.1039/DF9694700079

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements