A review of material design for high performance triboelectric nanogenerators: performance improvement based on charge generation and charge loss

As a type of innovative device, triboelectric nanogenerators (TENGs) are capable of converting mechanical energy into electrical energy through the triboelectric effect. Based on the working mechanism, the output performance of TENGs heavily relies on the triboelectric materials used. The modification of triboelectric materials is the most efficient way to improve the output performance of TENGs. Herein, this review focuses on the recent progress in triboelectric material design for high-performance TENGs. First, the basic theory of TENGs is introduced. Second, the relationship between the triboelectric materials and the output performance of TENGs is summarized in detail based on a theoretical model of the triboelectric charge dynamic equilibrium. Furthermore, the relevant strategies are analyzed in detail. Finally, challenges and shortcomings of the triboelectric materials for high-performance TENGs are discussed. This review provides a basis for the research status and future development of triboelectric materials.

5][36][37][38] However, the output performance of TENGs greatly depends on the dynamic equilibrium of triboelectric charge generation and charge loss; thus, simply increasing the triboelectric charge generation is not sufficient to further improve the output performance of TENGs. 39Triboelectric materials play a crucial role in determining the output performance of TENGs as it directly inuences triboelectric charge generation and charge loss. 40herefore, it is pivotal to study the working mechanisms of triboelectric materials in charge generation and charge loss to further improve the energy harvesting efficiency and expand the application range of TENGs.
Here, various material design strategies that improve the output performance of TENGs will be introduced accordingly, as shown in Fig. 1.First, the basic working modes of TENGs and the basic theory of TENGs are briey introduced.Second, the theoretical model of triboelectric charge dynamic equilibrium is described, and the relationship between the triboelectric materials and the TENGs' output performance is summarized.
Then, the relevant material-design strategies for improving the output performance of TENGs are described in detail, including surface engineering, inhibition of air breakdown, and utilization of charge dri.Finally, the current challenges in augmenting the output performance of TENGs are discussed, and a brief perspective on future opportunities is also provided.

Basic working modes of TENGs
3][54] Such transfer charge between two materials can be attributed to the interaction of their electron clouds. 55,568][59] The working principle of the vertical CS-mode TENGs is shown in Fig. 2a.When two different types of triboelectric materials come into contact, opposite triboelectric charges are generated on the surface of the dielectric material due to contact electrication (Fig. 2a(i)).When the two materials are separated by an external mechanical force, the triboelectric charges generated by contact electrication also separate and create an induced potential difference on the electrodes of the corresponding material, thereby causing a current pulse in the external circuit (Fig. 2a(ii)).When the two materials are subjected to separation and contact under an external force, the potential difference between the electrodes disappears, the electrons ow back to the original electrode, and a reverse current pulse occurs in the external circuit (Fig. 2a(iv)).By repeating this contact-separation process, TENGs can continuously generate alternating current output in the external circuit.
The other three working modes are shown in Fig. 2b-d.In the case of SE mode (Fig. 2b), when the triboelectric material approaches or leaves the electrode, charges will transfer from the electrode to the tribo-layer with high electron-withdrawing ability.As a result, an induction current is created in the electrode to balance the electrical potential.1][62][63] Fig. 2c shows a schematic diagram of the LS mode TENGs.The LS mode TENGs are based on the contact sliding between two tribolayers.When the two tribo-layers slide against each other under an external force, the charges on the tribo-layers also separate and create a potential difference between the two electrodes.When the external circuit is connected, electrons will ow from one electrode to the other due to the existence of a potential difference, forming an electric current.Therefore, the LS mode TENGs are able to collect many forms of mechanical energy, such as human movement and mechanical vibration, and convert it into electrical energy for driving small electronic devices. 64The schematic diagram of the FT mode TENGs is shown in Fig. 2d.The reciprocating slide of the independent tribo-layer on two stationary tribo-layers will cause a potential difference between two bottom electrodes, which drives electrons to ow back and forth between the two electrodes through an external circuit load.In this mode, the triboelectric charge can remain on the surface of the tribo-layer for a longer period, which enables stable output and high energy conversion efficiency. 65,66

Basic theory of TENGs
The theoretical source of TENGs comes from Maxwell's displacement current.In general, Maxwell's displacement current can be dened as follows: where D is the displacement eld, E is the electric eld, P is the electric eld, and 3 0 is the vacuum permittivity.However, in the case of TENGs, triboelectric charges generated by the physical contact between two different materials also contribute to the displacement current. 67Therefore, to account for the inuence made by triboelectric charges, Wang et al. added an additional polarization density term P S in D and extended Maxwell's equations. 68,69The specic Maxwell's displacement current in TENGs is as follows: The rst two terms on the right side of eqn (2) are induced currents generated by changing electric elds, which is the theoretical basis of the electromagnetic wave existence. 70,71The nal term is the current caused by the polarization eld generated by the electrostatic charge on the surface, which is the theoretical source of TENGs. 203][74][75] Here, as the CS mode is the most commonly designed, taking the CS mode as an example, the basic output parameter of TENGs can be deduced by a planar plane capacitance model (Fig. 2e). 73As shown in Fig. 2e, the vertical CS mode normally consists of two electrodes and two tribo-layers.The two tribo-layers have thicknesses of d 1 and d 2 and dielectric constants of 3 1 and 3 2 , respectively.The distance between two tribo-layers is dened as x(t) and changed by the external mechanical force.When the two tribo-layers are contacted by an external force, the inner surface of the two tribo-layers will produce the same amount of positive and negative charge, respectively.During the separation of the two tribo-layers, an air gap is formed between the two tribo-layers, and the induced potential (V) between the two electrodes is generated.The transferred charge between metal 1 and metal 2 is Q.By using Gauss's theorem, the induced potential (V) between the two electrodes can be given by: 73 where 3 0 is the vacuum permittivity, and E 1 , E 2 , and E air are the electric eld intensity inside dielectric 1, dielectric 2, and the air gap, respectively.From eqn (3), at an open-circuit condition, there is no charge transfer, so Q = 0. Therefore, the open-circuit voltage (V OC ) is given by: 73 In the short-circuit condition, V = 0. Therefore, the transferred charges (Q SC ) and short circuit current (I SC ) are: 73 3 The relationship between the TENG's output performance and triboelectric materials In the actual testing process, the TENGs achieve a maximum output performance only when the triboelectric charge generation and charge loss reach a dynamic equilibrium.In order to further improve the output of TENGs, a theoretical model about the dynamic equilibrium was proposed by Zhang et al., as shown in Fig. 3a. 39In this model, the triboelectric charge generated on the surface of the triboelectric materials can be moved or stored within the materials to accumulate the charge and then improve the output performance of TENGs.Additionally, the triboelectric charges can diffuse into the atmosphere or transfer to the bottom electrode, which then inuences the output performance.Therefore, the key factor limiting the maximum TENGs' output performance is not only the triboelectric charge generation, but also the triboelectric charge loss.Charge generation is closely related to the electron withdrawing/donating abilities of triboelectric materials.Among these, the electron withdrawing/donating abilities of triboelectric materials mainly depends on their chemical structure.][78][79][80] However, only a limited number of polymers adhere to these correlations.In 2019, Zou et al. built a standardized quantied triboelectric series by summarizing the measurement results of over 50 triboelectric materials. 81The triboelectric series can help researchers choose the best material pairs for high performance more carefully.Furthermore, the contribution of functional groups on triboelectric materials to the contact electrication effect is also recognized and proposed. 82In summary, there are various ways to modify the triboelectric properties of triboelectric materials: surface morphological modication, chemical modication, nanocomposite, and charge injection (Fig. 3b(i)).
Charge loss can be divided into two subprocesses: air breakdown and charge dri. 40,835][86] For air breakdown, it is important to select the appropriate material and structure design to reduce the voltage and limit the air breakdown, thus improving the output performance of TENGs, as shown in Fig. 3b(ii).In addition to air breakdown, triboelectric charge dri is also a major mode of triboelectric charge loss.Fig. 3b(iii) presents the strategy for the utilization of charge dri.During the working process of TENGs, the triboelectric charges generated on the surface of materials can transfer to the bottom electrode and achieve the utilization of the transferred charges, thus enhancing the TENGs' output performance. 46,87n summary, the process of contact electrication can be divided into three steps: triboelectric charge generation, charge storage, and charge loss.All these steps are mainly related to the triboelectric materials.TENGs can retain a high output performance by improving the surface charge density, inhibition of air breakdown, and utilization of charge dri through triboelectric material design.
4 Material design for improving surface charge density

Surface morphological modication
Surface morphological modication is the most commonly used method to improve the output of TENGs, which primarily involves building micro/nanostructures on the tribo-layer surface.The micro/nanostructures can efficiently improve the output by increasing the contact area.
Owing to its simple and low-cost production process, the template method has been widely used to construct micro/ nanostructures on the tribo-layer surface.Fig. 4a shows TENGs with three types of regular and uniform polymer patterned arrays (line, cube, and pyramid) prepared by the template method, 18 which improve the output performance of the TENGs by increasing the triboelectric effect and the capacitance change.Similarly, in Fig. 4b, Lai et al. proposed a stretchable and compliant triboelectric robotic skin with triangular microprism structure tribo-layer. 88The tribo-layer with triangular micro-prism surfaces simultaneously possesses excellent stretchability and excellent sensitivity in low-pressure regimes.Additionally, Choi et al. fabricated a pattern assisted triboelectric replicable nanogenerator with nanoscale surface-relief features (nano-PATERN) by using thermal nanoimprinting (Fig. 4c). 89The test results show that the nano-PATERN confers higher electrical output performance compared with the at-PATERN.
Researchers also constructed micro/nanostructures on the surface of the tribo-layer by laser ablation.Compared with the template method, laser ablation yields greater accuracy and a shorter working period for creating the pattern on the surface.As shown in Fig. 4d, Huang et al. fabricated different micro/ nano structures on the Cu and PDMS lms by laser ablation technology. 90Laser scanning ablation technology is used to create micro/nano dual-scale structures in stripes and cones on Cu lm surfaces.Additionally, micro-bowl structures in various sizes are fabricated on polydimethylsiloxane (PDMS) surfaces through single pulse irradiation.This unique surface topography effectively increases the contact area and achieves a 21fold increase in power density compared to the TENGs without

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Review micro/nano-structures.Fig. 4e shows the fabrication procedure of a lm-sponge-coupled TENG (FS-TENG) via direct ultraviolet laser ablation proposed by Cho et al. 91 Various surface structures can be created on the surface of the PI lm in one minute by ultraviolet laser ablation.Next, a sponge made from nonwoven polyamide and silicone rubber is designed to have full contact with the micro-/nano-scale structures on the surface of the PI lm.The FS-TENG demonstrates an open-circuit voltage of 48.19 V and a short-circuit current of 1.243 mA, reecting a threefold improvement in electrical performance compared to the FS-TENG with a pristine PI lm.The methods mentioned above are generally used to make regular micro/nanostructures, while methods such as the electrostatic spinning process and others are used to build irregular micro/nanostructures on the surface of the tribo-layer.Sun et al. reported a fabricating nanober-based TENG (NF-TENG) (Fig. 4f). 92The NF-TENG consisted of the electrospun PA66/ MWCNTs nanobers lm serving as the tribo-positive layer and the electrospun PVDF nanobers lm serving as the tribonegative layer, respectively.Electrospun bers offer the benets of uniformity, high porosity, and a large surface area, which improves the output performance of TENGs.Xie et al. used the dynamic supercritical carbon dioxide (scCO 2 ) foaming technique to fabricate TPU foams with micro-sized pores, as shown in Fig. 4g. 93The biomimetic wrinkles that are induced by the scCO 2 ow eld facilitate contact electrication and greatly enhance the triboelectric output performance.
The detailed output performance comparison of TENGs before and aer the surface morphology modication is shown in Table 1.In summary, the surface morphological modication can efficiently enhance the output performance of TENGs.The modied TENG can collect energy from various mechanical movements more efficiently, making it suitable for a wider range of application scenarios.However, the method provides only minimal performance improvement and a limited impact on the electron withdrawing/donating ability of triboelectric materials.Therefore, in the following review, we will introduce several strategies to improve the electron withdrawing/donating abilities of triboelectric materials.

Chemical modication
Chemical modication refers to introducing chemical functional groups on the surface of the triboelectric material by chemical reaction, which aims to change the electronic structure of the material and thereby increase the transferred charge during friction.
Importing appropriate chemical functional groups is the key to improving the output performance of TENGs.Fluorine has garnered signicant attention from researchers due to its strong  95 The modication uses a gas mixture of carbon tetra-uoride (CF 4 ) and oxygen (O 2 ) as the plasma source.The plasma etching not only resulted in surface uorination, but also developed micro/nanostructures on the surface of the PET lm.Therefore, the TENG based on the modied PET lm achieved a maximum V OC of z220 V, an I SC of z45 mA, and an induced  Nanoscale Advances Review charge of z130 nC, which are much higher than the unmodi-ed PET lm.Except for plasma etching, electrostatic selfassembly was also used to introduce the chemical functional groups.Based on the electrostatic self-assembly, Yang et al. imported the molecule 1H,1H-peruoro-octylamine (F 15 -NH 2 ) as the chemical functional group onto the surface of the PDMS layer (Fig. 5b). 41Peruoroalkyl chains have a tendency to accumulate at the air interface due to their high electronegativity, which improves the charge transfer efficiency between the electrode and tribo-layer.The V OC , I SC , and power density of the TENG based on the treated PDMS lm are 1392 V, 158.4 mA, and 57.1 W m −2 , respectively.The reports mentioned above have shown that surface uorination is an efficient method to increase the output performance of TENGs.Moreover, the output performance of TENGs is also affected by the molecular structures of uorinated polymers and the number of uorine units.Kim et al. synthesized a TENG based on uorinated polymers with different kinds of uorine units (Fig. 5c). 96The results show that the dielectric constant and the triboelectric performance of the uorinated polymers increase with increasing uorine units.
In addition to the uorinated group, the researchers introduced different kinds of chemical functional groups on the tribo-layer surface.As shown in Fig. 5d Interestingly, based on its excellent triboelectric properties, the TENG based on PI-b-C 60 also performs well in non-contact applications.Furthermore, Shin et al. introduced a series of halogens on the surface of the PET lm. 100 The PET surface was functionalized with halogen (Br, F, and Cl)-substituted phenyl or aminated molecules, resulting in a diverse range of triboelectric properties.Importantly, testing results show that the transferred charge density was arranged in the order of electron affinity.In 2019, Lee et al. prepared sulfur backbone-based inorganic polymers. 101Based on the high electron affinity of sulfur, the open-circuit voltage output of the TENG can reach 1366 V and light 630 LEDs under a minimal external force of ∼30 N.Moreover, Yao et al. introduced nitro groups and methyl groups on cellulose nanobrils (CNF) to change the tribopolarities of CNF. 102Specically, due to the nitro group having excellent electron-absorbing ability and the methyl group having excellent electron-releasing ability, the methyl-CNF and nitro-CNF have tribopositivity and tribonegativity, respectively.The TENG, based on the methyl-CNF as the positive tribo-layer and the nitro-CNF as the negative tribo-layer, demonstrated an average voltage output of 8 V and a current output of 9 mA.
To deeply explore the effect of chemical modication on the surface charge density, Lei et al. decorated different chemical functional groups (including octadecanethiol (ODT), 3-mercaptopropyl trimethoxysilane (MPTMS), 2-mercaptobenzimidazole (MBI), 2-mercaptobenzoxazole (MBO), and 1-phenyl-5mercaptotetrazole (PMTA)) on AgNW-based transparent conductive lms by self-assembled monolayer (Fig. 5e). 98cording to the HOMO/LUMO theory, the low-lying LUMO of the acceptor will dominate the electron transport.The electronabsorbing ability follows the sequence: PMTA > MBO > MBI > MPTMS > ODT.Therefore, TENG based on the PMTA-modied PDMS layer achieved the best output performance, with the maximum V OC , I SC , and Q SC reaching 290 V, 22.6 mA, and 114 nC, respectively.As shown in Fig. 5f, Liu et al. introduced different functionalities (electron-withdrawing and electrondonating groups) on the cellulose nanobrils (CNFs). 99The charge density of CNFs is weakened by the introduction of electron-withdrawing groups and enhanced by the introduction of electron-donating groups.The strength of the electrondonating ability of each functional group is given by: -NH 2 > -SH > -CN > -CF 2 CF 3 .Similarly, Li et al. ranked the electronwithdrawing ability of halogen groups (in Fig. 5g). 82It follows the order: CH 3 < H < OH < Cl < F. This makes a great contribution to further elucidating the relationship between functional groups and the triboelectric effect.
The detailed output performance comparison of TENGs before and aer chemical modication is shown in Table 2.Among the results, 1-phenyl-5-mercaptotetrazole is the most effective chemical to improve the output performance of TENGs.However, it is important to note that the choice of chemicals and their application methods should be tailored to the specic type of TENG and the materials used.Additionally, the environmental impact and long-term stability of the chemicals should also be considered when enhancing TENGs' output performance.
In summary, the output performance of TENGs is greatly enhanced by the introduction of suitable chemical functional groups.3][104][105] Additionally, chemical modication broadens the range of available materials for highperformance TENGs. 95,1063 Nanocomposite 4.3.1 Simple blending.The dielectric constant of the triboelectric material also plays an important role in the output performance of TENGs.Doping nanomaterials into the polymer is an effective method to improve the dielectric constant of the triboelectric material, thereby improving the TENG's output performance.[107][108][109][110] By adding a small amount of 2D conductive nanomaterials (such as graphene and MXene) to the polymer matrix, the dielectric constant of the composite material will be signicantly improved due to the conductive two-dimensional planar structure of the materials and the insulating polymer together constituting many microcapacitors, improving the ability of the composite material to store charge.[111][112][113] As shown in Fig. 6a, Bhatta et al. doped MXene nanosheets into the PVDF matrix.114 The dielectric constant of the PVDF composite lm increased as the MXene concentration increased.For the MXene concentration of 25 wt%, the dielectric constant of the PVDF composite lm is 44.1, which is much higher than that of the pristine PVDF (13.35).Therefore, the demonstrated TENG based on the PVDF composite lm can reach maximum V OC , I SC , and transferred charge values of 724 V, 163.6 mA, and 182 nC, respectively.

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PDMS (Fig. 6b). 115The TENG based on a composite PDMS lm with a doped ZnSnO 3 concentration of 6 wt% achieved the best output performance, with an output current that was up to 6.2 times greater than that of the pure PDMS lm-based TENG.In Fig. 6c, Kim et al. added high permittivity CaCu 3 Ti 4 O 12 (CCTO) particles into butylated melamine formaldehyde (BMF). 42CCTO particles with a high permittivity of 7500 can induce a strong internal polarization within the dielectric material when subjected to an electric eld generated by triboelectric charges.Under identical electric eld conditions, the BMF-CCTO 1 wt% composite exhibited three times the internal polarization of pure BMF.A rotation-type freestanding mode TENG based on the BMF-CCTO 1 wt% composite lm generated a high RMS voltage and current density of 268 V and 25.8 mA m −2 , respectively.
In recent years, ferroelectric materials have attracted much attention because of their high dielectric constant and ferroelectric effect.Suo et al. prepared a novel hybrid piezo/ triboelectric nanogenerator based on the BaTiO 3 (BTO)/PDMS composite lm. 118The PDMS composite lm with a BTO concentration of 20 wt% showed the best performance due to its ferroelectric polarization strength and dielectric constant.This work conrmed that piezoelectric and triboelectric effects can coexist in a single material component and interact to improve the electric output performance.As shown in Fig. 6d, Seung et al. reported a nanocomposite material system that consists of a high-dielectric ceramic material, barium titanate (BTO), and a ferroelectric copolymer matrix, poly(vinylideneuoride-co-tri-uoroethylene) (P(VDF-TrFE)). 116The surface charge potential dramatically increased due to the electrically induced ferroelectric polarization inside the P(VDF-TrFE) with dielectric BTO NPs.Under the combined action of triboelectric and ferroelectric effects, the TENG based on BTO/PVDF-TrFE composite lms achieved a boosted power-generating performance that improved by about 150 times compared with typical triboelectric material-based devices.Li et al. selected BaTiO 3 nanoparticles (BTO NPs) as the doping material, which was dispersed into the PI matrix, as displayed in Fig. 6e. 117Interestingly, the ideal doping mass concentration of BTO NPs for maximizing the electrical performance depends on the operating mode of TENGs.For LS-TENG, 5 wt% BTO NPs show the best performance, doubling the steady-state open-circuit voltage compared to that of the pure PI lm.Similarly, 18 wt% BTO NPs display the best results for CS-TENG with the steady-state open-circuit voltage doubled compared with the pure PI lm.
4.3.2Multilayer structure of the composite lm.0][121] However, it is a challenge to uniformly disperse high-dielectric nanomaterials in polymers. 122A valid way to achieve a high dielectric constant and output performance is by fabricating high-dielectric nanomaterials/polymer composites with multilayer structures.Firstly, interfacial polarization can form at the interfaces between different layers, resulting in charge accumulation at the multilayer interfaces and enhancing the dielectric constant.
Secondly, polymer lm on the high dielectric constant layer surface can effectively inhibit breakdown and charge leakage.Last but not least, the multilayer structure prevents high dielectric material agglomeration and minimizes defect formation.
Ravichandran et al. developed a multilayer exible composite structure by employing an insulator-metal-insulator architecture in place of a single insulator material (in Fig. 7a). 123he multilayer composite structure consists of an intermediate gold (Au) metal inclusion sandwiched in-between a charge generation and retention layer, parylene-C (PaC), and poly-tetrauoroethylene (PTFE).The metal inclusion acts as a charge storage site and its storage is several orders of magnitude greater than that of the bare insulator, enabling it to accumulate the triboelectric charge generated at each cycle.Based on the unique structural design, the TENG exhibited great output performance, resulting in a maximum charge density of 1076.56 mC m −2 and a maximum output power density of 4.8 W m −2 .In Fig. 7b, Pang et al. fabricated a TENG based on a sandwichstructured polyimide (PI)/boron nitride nanosheet (BNNS)/PI nanocomposite lm (PBP). 124The introduction of the BNNS interlayer signicantly enhances the triboelectric performance of the PI nanocomposite lm.Aluminum (Al) and PBP multilayers were used as the positive and negative contacting triboelectric layers, respectively.The short-circuit current of the TENG based on the PBP multilayer was 4.5 mA, which was 5 times that of the TENG without the BNNS interlayer.In addition, at an external load resistance of 10 MU, the TENG based on the PBP multilayer achieved a maximum power density of 21.4 mW cm −2 .
Similarly, to increase the TENG's output power, Chai et al. prepared multilayered ferroelectric nanocomposites (MFNCs) as negative tribo-layer, as shown in Fig. 7c. 49A conductive interlayer (multiwalled carbon nanotube (MWCNT) lled P(VDF-TrFE)) was sandwiched in two ferroelectric nanocomposites (BaTiO 3 /P(VDF-TrFE)).The output performance of the TENG was greatly improved, resulting in a maximum transferred charge density and power density of 105.70 mC m −2 and 7.21 W m −2 respectively, at 2 Hz, due to the enhanced polarization of ferroelectric materials by introducing a conductive interlayer.Moreover, the conductive interlayer can also trap triboelectric surface charges.Additionally, Cao et al. prepared X-Y-X sandwich structured copper calcium titanate/polyimide (CCTO/PI) nanocomposites for TENG by using a layer-by-layer casting method. 126In the X-Y-X sandwich-structure, polyimide (PI) with a high dielectric constant copper calcium titanate (CCTO) and pure PI lm were used as the outer layer and charge storage layer, respectively.By introducing a chargestorage layer of PI, the output performance was also improved.The V OC , I SC , and Q SC values of the TENG based on the X-Y-X sandwich-structure were 96.6 V, 5.6 mA, and 30.8 nC, respectively.
Ferroelectric composites have been found to improve the performance of TENGs, but their output performance is hindered by randomly dispersed particles.Therefore, Park et al. introduced a high-performance TENG based on ferroelectric multilayer nanocomposites with alternating poly(vinylideneuoride-co-

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Nanoscale Advances triuoroethylene) (PVDF-TrFE) and BaTiO 3 (BTO) nanoparticles (NP) layers, as shown in Fig. 7d. 125From the COMSOL Multiphysics result, it is clear that the multilayer structure featuring BTO NPs on the coplanar layer facilitates a more efficient connectivity of interfacial charges at closer distances compared to composites with randomly dispersed BTO NPs, which leads to a signicantly enhanced local eld while boosting the ferroelectric polarization of the polymer.Moreover, with characteristics that induce stress concentration, the dielectric constant of multilayers consisting of alternating so/hard layers surpasses that of single PVDF-TrFE/BTO nanocomposites (15.9) and pure PVDF-TrFE lms (13.9).Consequently, the multilayered TENG showed 2.3 and 1.5 times higher current densities than pure PVDF-TrFE and PVDF-TrFE/BTO nanocomposites without a multilayer structure, respectively.The detailed output performance comparison between TENGs based on a pristine polymer and TENGs based on a composite lm is shown in Table 3.Among the results, the TENG based on ferroelectric materials/polymer composite lms shows the best output performance by coupling the triboelectric effect and the piezoelectric effect.Additionally, the TENG based on the multilayer structure has better output performance compared with the TENG based on single blending (single layer).Thus, the surface charge density of the triboelectric   Review Nanoscale Advances materials is effectively enhanced by doping nanomaterials into the polymer.By designing a multilayer composite membrane structure, the dielectric properties of the single-layer composite lm are efficiently improved.Furthermore, the coupling of the triboelectric effect and piezoelectric effect is achieved by doping ferroelectric nanoparticles, thereby efficiently increasing the surface charge density and hence boosting TENGs' output performance.

Charge injection
The output performance of TENGs is strongly inuenced by their surface charge density.Injecting charge into the surface of the tribo-layer is the most direct and effective way to increase the surface charge density.Wang et al. utilized an air-ionization gun to bring the negative charges onto the surface of a FEP lm (Fig. 8a). 134The air-ionization gun could generate positive and negative charges by ionizing air inside the gun.To monitor the negative charges on the FEP surface, researchers used a Coulomb meter to measure the charge ow from the ground to the bottom electrode.The result shows that each ion injection event transfers charges with a charge density of approximately 40 mC m −2 from the ground to the bottom electrode, introducing charges of the same density onto the FEP surface.Aer the 17 consecutive instances of charge injection, the negative static charge density on the FEP surface nally reached ∼630 mC m −2 .In this study, the maximum surface charge density for the CS-mode TENGs can be determined by comparing the threshold voltage for the air breakdown with the actual voltage drop (V gap ) across the air gap.The V gap has the following relationship with the gap distance (x): 134 where d is the thickness of the FEP lm, 3 r is the relative permittivity of the FEP layer, s 0 is the surface charge density, and 3 0 is the vacuum permittivity.The air breakdown voltage (V AB ) curve can be described according to the empirical formula of Paschen law: 137-139 where P is the atmospheric pressure, x is the gap distance, and A and B are the constants determined by humidity, temperature, etc. in the environment.During the contact-separation process, to obtain the maximum surface charge density, the V gap must be smaller than the V AB .Therefore, in the whole contact-separation process, the relationship between V gap and V AB should be satised for: 134 AðPxÞ According to eqn (8), the maximum surface charge density (s max ) for the CS-mode TENGs is: From this equation, it is proposed that thinner dielectric lms are the preferred choice for achieving a higher surface charge density.Liu et al. introduced the surface charges to the surface of different polymer lms using an air-ionization gun to investigate the surface charge decay trend of the TENGs in a high-humidity environment. 140It was discovered that increasing the hydrophobicity of dielectric materials can lead to higher surface charges, particularly in high humidity conditions.The TENG based on the PTFE lm retained 90% of its initial output performance aer 5000 cycles under 90% relative humidity.
In addition to the air-ionization gun, a corona discharge treatment (CDT) can be used to deposit charges onto the surface of the tribo-layer.As shown in Fig. 8b, Park et al. reported an Ag nanowire (NW)-embedded laminating structure (AeLS) for ionic charge injection by CDT. 43Based on their unique laminated structure, Ag nanowires dissipate positive charges, allowing negative ions to accumulate on the outermost surface.The testing results show that the AeLS with CDT exhibited higher durability and resistance to moisture and water molecules.The output current, charge, and power density of the TENG based on AeLS were z146 mA, z300 nC, and z1.6 W m −2 , respectively.In addition to introducing charges onto the surface of the tribolayer, the corona discharge treatment can optimize the polarization of triboelectric materials.Sun et al. enhanced the interfacial polarization of the chitosan blends by corona charge injection to enhance the output performance (Fig. 8c). 135During the corona charge injection, the ion in the chitosan blends will move in the direction of the electric eld, which leads to enhanced polarization and then increases the dielectric constant of the chitosan blends.Therefore, aer corona charge injection, with the increasing dielectric constant and surface charge density, the TENG based on the treated chitosan blends exhibited an output voltage that is 25 times (200 V) higher than that of the TENG based on the initial lm.
In another study, Cha et al. proposed the improvement of the output performance of TENGs through introducing charge to the gradient charge-connement layer based on electrospinning bers by high-voltage charge injection (HVCI), as displayed in Fig. 8d. 136Each successive nanobrous layer in the gradient charge-connement layer included a larger number of mesoporous carbon spheres (mCSs) in increasing size.The gradient distribution of mCSs facilitated the movement of injected charge from the surface to the inner layers of the nanobrous structure.When an external eld of 7 kV was applied upon charge injection, the surface charge density on the gradient-charge connement layer increased approximately 7.5 times compared to the case without mCSs.Consequently, the output voltage of the TENG was 600 V aer charge injection, which represented an increase of z40 times compared to the output before charge injection.
However, the traditional charge injection process is more complex compared to the simple contact electrication process, and may require additional equipment support, such as an airionization gun, a high-voltage source for corona charge injection, and others.Therefore, developing a new simple charge injection method is urgent.
In recent years, Wu et al. reported a simple and effective surface charge injection technology through a half-wave charge excitation circuit (CEC) (Fig. 9a). 50In previous work, it has been conrmed that the CEC can be used to improve the surface charge density of TENGs.In this research, the half-wave charge excitation circuit was used to provide a stable, high excitation voltage to achieve air breakdown and thus charge injection.A smaller capacitance in the CEC is benecial for achieving a higher excitation voltage to improve the charge injection efficiency.Interestingly, the injected charge polarity on the surface of the dielectric polymers can be controlled by adjusting the connection mode of the CEC.Aer parameter optimization, the TENG based on the PI lm reached an ultrahigh output charge density of 880 mC m −2 through this technology.Moreover, they also established a charge transfer model to quantify the surface charge density.This study enhances the understanding of the output charge density of TENGs, which is essential for enhancing the TENG performance.
Additionally, Guo et al. designed a high-performance TENG based on a charge reversion process generated by the electrostatic breakdown effect (Fig. 9b). 37This report used the high voltage generated by the voltage-multiplier circuit (VMC) to cause an electrostatic breakdown effect.The charge-reversion process could be divided into four stages.In the initial stage, the tribo-layer (PTFE lm) carries a small amount of negative charge.In the second stage, the TENG starts charging the capacitors in the VMC, and the gap voltage of the TENG also starts to increase.In the third stage, with the increasing gap voltage of the TENG, the electric eld between the upper electrode and the dielectric lm of the TENG eventually reaches the threshold for air breakdown to occur, which leads to positive charge being transferred to the surface of the dielectric lm.Therefore, in the fourth stage, when the VMC is removed, the surface charges of the dielectric lm are reversed to a positive polarity.Based on the charge reversion process, the surface charge density of the PTFE-based TENG increased from 97 mC m −2 to 780 mC m −2 , which surpassed the theoretical limit from Paschen's law.
The dissipation of the injected surface charge is still a limitation for charge injection.To improve the stability of the

Review
Nanoscale Advances surface charge introduced by excessive charge self-injection, a step-by-step discharge mitigation strategy was proposed by Zhao et al., as shown in Fig. 9c. 141They induced air ionization for charge injection onto the surface of the dielectric material by utilizing the directional high electric eld generated by the charge excitation strategy of the voltage-multiplying circuit.At the operating frequency of 1.5 Hz, the injected charge on the dielectric lm could be saturated in 22 seconds by using the charge excitation strategy.As shown in Fig. 9c(i), when the gap voltage of CS-TENG is higher than the air breakdown voltage, the discharge phenomenon occurs between the dielectric material and the electrode, leading to charge loss.Therefore, to reduce charge loss, a paralleling external capacitor was used to decrease the gap voltage of CS-TENG and then retain the maximum charge on the dielectric material surface, as displayed in Fig. 9c(ii).Based on the step-by-step discharge mitigation strategy, aer charge injection, the TENG based on 7 mm thick PI lm obtained an ultrahigh charge density of 1480 mC m −2 under the condition of 5% relative humidity.
To better demonstrate the current situation of charge injection, we compared the output performance of the TENGs before and aer charge injection in Table 4.As can be seen from the output performance of TENGs in Table 4, these advanced methods of charge injection signicantly improve the output performance of TENGs compared to TENGs without charge injection.According to the latest research, the charge selfinjection strategy (charge injection technology through a halfwave charge excitation circuit) is the most effective way to improve the output performance of TENGs.Compared with the traditional charge injection method, it can achieve a higher surface charge density.With all that said, regardless of the used material, charge injection can increase the surface charge density of the triboelectric materials by directly increasing the number of charges.However, the injected charge is easily dissipated, which severely limits the application of charge injection in TENGs.

Materials design for controlling charge loss
Except for charge generation, charge loss is also an essential factor that determines the output performance of TENGs. 139,145harge loss can be divided into two parts: air breakdown and charge dri in the triboelectric materials. 39,83In this section, we will introduce two strategies to improve the output performance of TENGs: inhibition of air breakdown and utilization of charge dri.

Inhibition of air breakdown
In the actual TENGs output test, air breakdown is widespread and greatly affects the output performance of TENGs.Wang et al. utilized a dual dielectric layer to inhibit air breakdown. 139VDF is chosen for the air breakdown suppression layer due to its high relative permittivity, while PI is chosen for the dielectric charge leakage suppression layer because of its low dielectric charge leakage.By simultaneously suppressing air breakdown and dielectric charge leakage, the maximum peak power density at 2 Hz is 61.3 W m −2 and the output charge density of the TENG is 2.2 mC m −2 .To suppress air breakdown under high charge density conditions, Liu et al. demonstrated a new triboelectric polymer, poly(vinylidene uoride-triuoroethylene-chloro-uoroethylene) (P(VDF-TrFE-CFE)). 146The high dielectric permittivity of P(VDF-TrFE-CFE) can inhibit air breakdown.The increased upper limit of air breakdown in TENGs leads to unprecedented levels of charge density and energy density.The charge density and energy density of the TENG can reach 8.6 mC m −2 and 0.808 J m −2 per cycle, respectively.These studies effectively suppressed air breakdown in the TENG, preventing triboelectric charge decay and boosting the TENG output.
Recent studies indicate that air breakdown is inevitable when the TENGs work in the air and limits the maximum surface charge density of the TENG. 147,148In addition to the working environment, the working mode of TENGs has an inuence on air breakdown. 84,149Especially in freestanding triboelectric-layer (FT) mode, air breakdown greatly limits the output performance of the TENG.
In a recent study, Deng et al. reported a ternary electrication layered architecture TENG (TEL-TENG) system to inhibit air breakdown, as shown in Fig. 10a. 44Compared with previously reported binary electrication layered TENG (BEL-TENG), the upper rotator of the TEL-TENG is constructed by using copper and uorinated ethylene propylene (FEP) as the two kinds of triboelectric materials and another triboelectric material Kapton was used for the stator of the TEL-TENG.Based on the unique structure design, the output performance of the TEL-TENG has been greatly improved, which leads to a 2.5-fold enhancement of the peak power compared to a BEL-TENG consisting of copper and FEP.Moreover, as the simulation results illustrate in Fig. 10b, a ternary electrication layered architecture can effectively reduce the electric eld and then inhibit air breakdown.Additionally, in 2021, Li et al. proposed a polyester fur-reinforced rotary triboelectric nanogenerator (PFR-TENG), as displayed in Fig. 10c. 45This report also used the ternary electrication layered architecture, and polyester fur was chosen as the third triboelectric material.The PFR-TENG electric output remained at 100% aer 100k cycles of continuous testing using partial so-contact and non-contact modes, effectively reducing abrasion on the dielectric layers' surface and improving the stability of the TENG.
The ternary electrication layer (TEL) structure has been proven to be helpful in improving the output performance of TENG. 44,45However, air breakdown could also occur on the interface of the tribo-layers, which limits the maximization of the output of the TEL-TENGs.Therefore, to further improve the TENG's output, in 2023, An et al. reported a new design of TEL-

Nanoscale Advances Review
Table 5.From Table 5, it is clear that high-dielectric polymers can achieve high output performance by inhibiting air breakdown.Additionally, TENGs based on the FT working mode with a ternary electrication layered architecture have realized high output performance by inhibiting air breakdown.Inhibition of air breakdown has been achieved based on the triboelectric  Review Nanoscale Advances effect between three types of triboelectric materials, providing a new direction to reducing charge loss through material design.

Utilization of charge dri
In previous studies, the leakage current of the tribo-layer has been a key factor limiting the output performance of TENGs.However, in recent research progress, researchers have started to use the leakage current of the tribo-layer to achieve charge migration and then improve the output of the TENG.In 2018, Lai et al. investigated the transport and storage process of triboelectric charges in the tribo-layer by embedding criss-crossed gold layers in the near-surface of the tribo-layer. 121he main dynamic motion for triboelectric charges in the tribolayer is the dri process caused by the electric eld, and the direction of this process is vertically downward (from the surface to the inside of the material).The dri process of triboelectric charges decreases the surface charge density of the tribo-layer, which contributes to the further accumulation of triboelectric charges on the surface.The charge density of the TENG reaches 168 mC m −2 , which is nearly 4 times the value of the TENG based on the pure polymer.
Fu et al. reported a high output performance and durability of TENG by changing the dielectric surface effect into a volume effect through the leakage current of the millimeter-thick porous polyurethane (PU) foam lm (Fig. 11a). 46The high leakage property of the porous lm allows it to transfer electrical charges from the surface to the inside of the material, thus realizing high charge migration.Utilizing the strong charge migration characteristics of the porous PU foam lm, the average power density of the TENG increased to 20.7 W m −2 Hz −1 .Moreover, aer 200 000 cycles, the output performance of the rotary-mode TENG did not change signicantly, which showed high durability.This study offers a novel method to enhance TENGs' output performance and broaden the selection of materials for high-performance TENGs.Similarly, as shown in Fig. 11b, Sun et al. introduced multi-walled carbon nanotubes (MWCNT) in polyurethane (TPU) to realize charge migration. 47The charges generated by contact electrication could be transferred from the surface of the TPU to the interior due to the excellent electrical conductivity of the MWCNT.Moreover, with the increasing content of MWCNTs, the electrical conductivity of MWCNT/TPU sharply increased, which led to strong charge migration.Based on the above characteristics, the short-circuit current of the TENG based on the MWCNT/ TPU composite lm improved by 100 times compared to the traditional dielectric TENG.Furthermore, even in high humidity environments, this TENG could maintain a stable output.Similarly, Wu et al. utilized the hysteretic and ordered charge dri behavior of dielectric polymers to construct TENGs with a stable and continuous (SC) output ability (SC-TENG). 87nder the action of the triboelectric electric eld, the charge generated by triboelectrication migrates directionally from the surface to the inside of the polyurethane (PU) due to its high leakage property.Additionally, using a 1 mm-thick PU lm ensures both excellent wear resistance and high output performance of the TENG.
In addition, charge migration can be used to achieve highperformance DC output.By coupling the charge migration and the ternary dielectric triboelectrication effect, Li et al. developed a DC-TENG with improved output performance, as shown in Fig. 11c. 48Aer continuous friction, a lot of positive and negative charges accumulated on the surfaces of the PA and PTFE lms, respectively.The leakage current occurred between the electrode and PA lm due to the high electric eld, resulting in a DC output in the external circuit.The testing results show that the charge density output has a highly linear relationship with the leakage current of the positive tribo-layer.Moreover, the electronegativity of the triboelectric material is also vital for the charge density output.Therefore, they established the ternary dielectric evaluation rules for material selection and improving performance.Aer parameter optimization, the DC-TENG based on PA/PET/PTFE achieved an ultrahigh average power density of 6.15 W m −2 Hz −1 .Similarly, Zhang et al. proposed a novel insulator-based quasi-tribovoltaic nanogenerator (I-Q-TVNG) with ultrahigh voltage and power by utilizing charge dri in the dielectric material. 152This I-Q-TVNG exhibits an ultrahigh output voltage of 2324 V and an average power of 11.8 mW.Additionally, it can maintain a nearly constant DC output with a crest factor of approximately 1.0204.
The detailed output performance of TENGs with the utilization of charge dri is shown in Table 6.Given the above, the triboelectric charges generated by triboelectrication can migrate from the surface of the material to the inside of the material through the selection of triboelectric materials with high leakage current, achieving utilization of charge dri and thus further output performance improvement.In conclusion, this work outlined the recent research in the development of material design for improving TENG's output performance.Strategies discussed for high surface charge density include surface morphological modication, chemical modication, dielectric material doping, and charge injection.Furthermore, methods for improving the TENG's output by inhibiting air breakdown and utilizing charge dri have also been discussed.This paper is of great signicance to the research of triboelectric materials, and also helpful to the practical research and innovation of TENGs.This review can signicantly contribute to the research on triboelectric materials and advance practical studies of TENGs.The challenges and future perspectives for improving the output performance of TENGs have been summarized below.

Challenges
(1) The fundamental mechanisms of contact electrication still need further research.Several hypotheses of contact electrication have been proposed, but a denitive conclusion has not yet been established.
(2) The coupling mechanisms between the triboelectric effect and other effects, such as the piezoelectric effect, photovoltaic effect and magnetization effect, need to be further systematically and comprehensively understood.
(3) The study of the leakage current of triboelectric materials for high-performance TENGs is insufficient.Most of the past research proposed that the leakage current of the material limited its output performance.However, a recent study shows that proper leakage current is benecial to the improvement of TENGs' output performance.
(4) The applications of TENGs in harsh environments.Triboelectric materials must be endowed with functional characteristics while maintaining their triboelectric properties to meet the diverse requirements of TENGs in different environments and then advance the commercial development of TENGs.

Future perspectives
Although progress has been achieved in enhancing the output performance of TENGs, more work is required to effectively address the remaining challenges.The strategies for improving the TENGs' output performance are prospected from the following aspects: the triboelectric material is the most important part of TENGs, which directly affects the output performance of TENGs.Additionally, the output performance of TENGs is affected by the environment, such as high humidity, high temperature, etc.Therefore, the ideal triboelectric material should have a high charge density, good mechanical stability, and environmental adaptability.New triboelectric materials need to be developed to obtain high-output performance in harsh environments.In high humidity environments, on the one hand, the properties of the triboelectric material can be changed by chemical modication so that it can maintain high output performance under high humidity conditions.On the other hand, it would also be a good choice to search for a material that can couple the triboelectric effect and the moisture-generating effect.At present, the most obvious technology to improve the TENG output performance is the power management system (PMS), which is one of the key technologies to realize the application of TENG technology.Some power management systems would provide a bias voltage to the friction material during operation.This bias voltage polarizes the triboelectric material, thus improving the output performance of TENGs.Composite lms (especially those lled with highdielectric nanoparticles) are also a promising research topic in this realm.
These important issues highlight great opportunities for researchers across different sectors to enhance the output performance of TENGs.The continuous technical innovation and theoretical research promote its application prospects in the eld of energy harvesting and self-powered sensing, which is crucial for the widespread commercial applications of TENGs.

Fig. 2
Fig. 2 Four basic working modes of TENGs: (a) vertical CS mode, (b) SE mode, (c) LS mode, (d) FT mode.(e) Schematic diagram showing the working principle of the vertical CS mode.

Fig. 3
Fig. 3 (a) Theory model of the triboelectric charge in dynamic equilibrium.Reprinted with permission from ref. 39.Copyright 2020, Elsevier.(b) Various materials-related strategies to improve the performance of TENGs.

Fig. 4
Fig. 4 (a) The fabrication process of the flexible TENG.Reprinted with permission from ref. 18.Copyright 2012, American Chemical Society.(b) The process of fabrication of the tribo-layer with triangular micro-prisms structure.Reprinted with permission from ref. 88.Copyright 2018, Wiley.(c) One-step fabrication process of the nano-PATERN using a thermal nanoimprint process.Reprinted with permission from ref. 89.Copyright 2015, Wiley.(d) Preparing micro/nano structures by femtosecond laser direct writing.Reprinted with permission from ref. 90.Copyright 2019, Elsevier.(e) Fabrication procedure of a TENG with a coupled structure using a direct UV laser-ablated film and soft composite of the sponge layer.Reprinted with permission from ref. 91.Copyright 2021, American Chemical Society.(f) Schematic preparation process of TENG incorporating electrospun PVDF and PA66/MWCNTs nanowires.Reprinted with permission from ref. 92.Copyright 2021, Elsevier.(g) The fabrication process of TENG by scCO 2 foaming.Reprinted with permission from ref. 93.Copyright 2023, Elsevier.

Fig. 5
Fig. 5 (a) Surface fluorination of the PET film by inductive-coupled plasma etching.Reprinted with permission from ref. 95.Copyright 2015, Wiley.(b) Using an electrostatically self-assembled molecule 1H,1H-perfluoro-octylamine (F 15 -NH 2 ) as the surface modification for the PDMS dielectric layer.Reprinted with permission from ref. 41.Copyright 2021, Royal Society of Chemistry.(c) TENGs based on fluorinated polymers with different kinds of fluorine units.Reprinted with permission from ref. 96.Copyright 2018, Elsevier.(d) Introduction of C 60 to the PI film.Reprinted with permission from ref. 97.Copyright 2021, Royal Society of Chemistry.(e) Decorating different chemical functional groups (CFGs) through the SAM treatment.Reprinted with permission from ref. 98.Copyright 2023, Elsevier.(f) Contact electrification performance of CNFs with chemically tailored molecular surface modification.Reprinted with permission from ref. 99.Copyright 2021, Elsevier.(g) Comparison of different functional groups on the contact electrification of polymers.Reprinted with permission from ref. 82.Copyright 2020, Wiley.
, Lee et al. fabricated a C 60 -containing block polyimide (PI-b-C 60 ) by the cycloaddition reaction of azide-containing PI with C 60 . 97C 60 is recognized as an effective electron acceptor molecule.Therefore, the PI-b-C 60 lm shows highly electronegative ability.The TENG based on PI-b-C 60 achieved a superior charge density of over 300 mC m −2 .

Fig. 6
Fig. 6 (a) Fabrication process of the PVDF/MXene composite film and property of PVDF with different MXene concentrations.Reprinted with permission from ref. 114.Copyright 2021, Elsevier.(b) Structure of ZnSnO 3 -PDMS-based TENG and schematic illustration of the charges in the molecular structure.Reprinted with permission from ref. 115.Copyright 2015, Elsevier.(c) Chemical structure of CCTO and the dielectric constant of the BMF-CCTO composite film under an electric field.Reprinted with permission from ref. 42.Copyright 2020, Wiley.(d) Schematic description of a ferroelectric composite-based TENG and KPFM study of the ferroelectric composite film.Reprinted with permission from ref. 116.Copyright 2017, Wiley.(e) The output performance of the BTO/PI nanocomposite film-based VCS-TENG and LS-TENG.Reprinted with permission from ref. 117.Copyright 2022, Elsevier.

Fig. 7
Fig. 7 (a) Design, structure, and working mechanism of the insulator-metal-insulator TENG.Reprinted with permission from ref. 123.Copyright 2020, Wiley.(b) A sandwich-shaped nanocomposite film-based TENG and the output performance of the TENG.Reprinted with permission from ref. 124.Copyright 2022, American Chemical Society.(c) The fabrication process and output performance of MFNCs.Reprinted with permission from ref. 49.Copyright 2022, Elsevier.(d) Schematic of the three different types of composite film and the FEM simulations of the electric field distribution in the single and multilayered PVDF-TrFE/BTO composite films.Reprinted with permission from ref. 125.Copyright 2020, American Chemical Society.

Fig. 8
Fig. 8 (a) Injecting negative ions onto the FEP surface from an air-ionization gun and the output performance of the treated FEP film.Reprinted with permission from ref. 134.Copyright 2014, Wiley.(b) Fabrication process of AeLS with i-CDT.Reprinted with permission from ref. 43.Copyright 2023, Wiley.(c) Schematic diagram of the corona charge injection and structure/working principle of the TENG.Reprinted with permission from ref. 135.Copyright 2022, Wiley.(d) Schematic of the fabrication process of the TENG and injection of the negative and positive charges to PTFE and nylon-11, respectively.Reprinted with permission from ref. 136.Copyright 2022, Wiley.

Fig. 9
Fig. 9 (a) Structure and principle of charge injection enabled by air breakdown achieved by a half-wave charge excitation circuit.Reprinted with permission from ref. 50.Copyright 2022, Wiley.(b) Theory analysis for the charge reversion process.Reprinted with permission from ref. 37.Copyright 2023, Royal Society of Chemistry.(c) Discharge mitigation strategy to decrease the dissipation of the injected surface charge.Reprinted with permission from ref. 141.Copyright 2023, Wiley.

141 ©
m −2 0.49 W m −2 --252 mC m −2 2.08 W m −2 143 Prior-charge injection PVDF 584 V 15.3 mA m −2 79 mC m −2 -1008 V 32.1 mA m −2 121 mC m −2m −2 960 V 350 mA m −2 (3 Hz) 1480 mC m −2 86 W m −2 2024 The Author(s).Published by the Royal Society of Chemistry Nanoscale Adv., 2024, 6, 4522-4544 | 4537 Review Nanoscale Advances TENG with a shielding layer and shrouded-tribo-area (SS-TEL-TENG) to prevent air breakdown (Fig. 10d). 150Air breakdown is effectively suppressed based on the grounded conductive shielding layer and the increased shrouded area.Through structure and material optimization, SS-TEL-TENG demonstrates a 3.59-fold increase in output charge compared to traditional S-TENG and a 1.76-fold increase compared to TEL-TENG.Additionally, the TEL structure can be used to improve the output performance of DC-TENG.As shown in Fig. 10e, Shan et al. proposed a multiple unit ternary electrication strategy based on triboelectrication and corona discharge. 151The triboelectric properties of the PU lm can be controlled by adding PTFE powder, resulting in the realization of its electropositivity/electronegativity during friction with PTFE/ Kapton.The output charge density of the optimized rotary TENG can reach 5.5 mC m −2 with an 82 mC transfer charge per round, which exceeds all previous sliding DC-TENG records.To illustrate the present development of inhibition of air breakdown in TENGs, we summarized the output performance of TENGs using different methods to inhibit air breakdown in

Fig. 10 (
Fig. 10 (a) Structural design of the TENG system and the electron-cloud-potential-well model during contact.(b) Schematics of the operating principle of the TENG system.Reprinted with permission from ref. 44.Copyright 2020, American Chemical Society.(c) The cross-section schematic of the TENG and the electron cloud potential well model for surface charge transfer.Reprinted with permission from ref. 45.Copyright 2021, Elsevier.(d) Structural schematic and output performance of TENG.Reprinted with permission from ref. 150.Copyright 2023, Wiley.(e) Structure of the ternary dielectric electrification TENG and SEM images of PU with/without PTFE powder.Reprinted with permission from ref. 151.Copyright 2024, Wiley.

Fig. 11 (
Fig. 11 (a) Dielectric volume effect-based TENG.Reprinted with permission from ref. 46.Copyright 2023, Wiley.(b) Schematic diagrams and charge dispersion of CN-TENGs with different MWCNT contents.Reprinted with permission from ref. 47.Copyright 2024, Wiley.(c) Conceptual diagram of the TENG and comprehensive selection rules of intermediate triboelectric materials.Reprinted with permission from ref. 48.Copyright 2023, Royal Society of Chemistry.

Table 2
The summary of TENG with chemical modification

Table 3
The summary of TENG with nanocomposite

Table 4
The summary of TENG with charge injection

Table 5
The summary of TENG with inhibition of the air breakdown