Issue 10, 2024

Lithium, sodium and potassium enolate aggregates and monomers: syntheses and structures

Abstract

In this Article, we report the syntheses and comparative structural studies of lithium, sodium, and potassium anthracen-9-yl enolates, as their aggregates (Li, Na: hexamer; K: tetramer) and ligand-stabilized monomers (for Li and Na). The monomers add new members to the rare collection of group-1 metal monomeric enolates. Moreover, the series covers different group-1 metal cations (Li+, Na+ and K+) and aggregate sizes, allowing comparative structural studies to elucidate how the metal identity and aggregate size influence the enolate structure.

Graphical abstract: Lithium, sodium and potassium enolate aggregates and monomers: syntheses and structures

Supplementary files

Article information

Article type
Paper
Submitted
23 Jan 2024
Accepted
09 Feb 2024
First published
12 Feb 2024
This article is Open Access
Creative Commons BY license

Dalton Trans., 2024,53, 4719-4728

Lithium, sodium and potassium enolate aggregates and monomers: syntheses and structures

N. Davison, J. M. Hemingway, P. G. Waddell and E. Lu, Dalton Trans., 2024, 53, 4719 DOI: 10.1039/D4DT00211C

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