Issue 11, 2024
From the journal:

Chemical Science

A decade of lessons in the activation of ArIL2 species

Tania, ORCID logo a   Marcus Sceney ORCID logo a  and  Jason L. Dutton ORCID logo *a  

* Corresponding authors

a Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia
E-mail: j.dutton@latrobe.edu.au

Abstract

Hypervalent iodine(III) compounds of the general structure ArIL2 are widely used as oxidizing agents for a variety of applications across both organic and inorganic chemistry. Considerable work has been done on the activation of these compounds by tuning the ligands at the iodine centre. This perspective summarises the work of our and other groups on rectification of historically misidentified iodine(III) reagents of this class, and the syntheses of activated species. Recent advances focusing on increasing the oxidative capacity of I(III) moieties using Lewis and Brønsted acids and Lewis bases as well as the activation of halogens with I(III) are discussed.

Graphical abstract: A decade of lessons in the activation of ArIL2 species

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Article information

DOI
https://doi.org/10.1039/D3SC06588J
Article type
Perspective
Submitted
07 Dec 2023
Accepted
08 Feb 2024
First published
09 Feb 2024
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2024,15, 3784-3799

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A decade of lessons in the activation of ArIL2 species

Tania, M. Sceney and J. L. Dutton, Chem. Sci., 2024, 15, 3784 DOI: 10.1039/D3SC06588J

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