Issue 2, 2024
From the journal:

Organic Chemistry Frontiers

Regio- and stereoselective hydrosilylation of alkynes with alkoxysilanes for the synthesis of β-(Z) vinylsilanes catalyzed by a dirhodium(ii)/XantPhos complex†

Liqun Yang,a   Wenkui Lu,a   Xiaoyu Wu,a   Yan Lu,a   Xiaomin Xie ORCID logo *a  and  Zhaoguo Zhang ORCID logo *a  

* Corresponding authors

a Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China
E-mail: xiaominxie@sjtu.edu.cn, zhaoguo@sjtu.edu.cn

Abstract

A Rh2(OAc)4/XantPhos ((9,9-dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphane)) catalyzed regio- and stereoselective hydrosilylation of alkynes with various tertiary silanes in acetonitrile represents a straightforward and highly effective strategy for the synthesis of β-(Z) vinylsilanes. This method exhibits remarkable compatibility with diverse functional groups, encompassing halides, nitriles, amines, esters, nitro compounds, and heterocycles.

Graphical abstract: Regio- and stereoselective hydrosilylation of alkynes with alkoxysilanes for the synthesis of β-(Z) vinylsilanes catalyzed by a dirhodium(ii)/XantPhos complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D3QO01725G
Article type
Research Article
Submitted
18 Oct 2023
Accepted
23 Nov 2023
First published
27 Nov 2023

Org. Chem. Front., 2024,11, 448-457

Permissions

Request permissions

Regio- and stereoselective hydrosilylation of alkynes with alkoxysilanes for the synthesis of β-(Z) vinylsilanes catalyzed by a dirhodium(II)/XantPhos complex

L. Yang, W. Lu, X. Wu, Y. Lu, X. Xie and Z. Zhang, Org. Chem. Front., 2024, 11, 448 DOI: 10.1039/D3QO01725G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements