Issue 2, 2024

Giant exchange bias field above room temperature in perovskite YbCr1−xFexO3 (x = 0.6–0.9)

Abstract

Temperature-induced exchange bias is observed in perovskite YbCr1−xFexO3 (x = 0.6–0.9) compounds. This is ascribed to the ferromagnetic (FM) coupling between Fe3+/Cr3+ ions and Yb3+ ions. During demagnetization, the Yb3+ ions will show a tendency to rotate with the direction of the applied magnetic field. However, the antiferromagnetic coupling of Fe3+/Cr3+ ions has a pinning effect, hindering their rotation, and thus producing an exchange bias effect. With increasing Fe3+ ion content, the magnetization and exchange bias field gradually become larger. When x = 0.8 and 0.9, the exchange bias field reaches up to −9.7 kOe and −13.6 kOe at 300 K, respectively. This giant room temperature exchange bias field will be more conducive for practical applications in magnetoelectronic devices.

Graphical abstract: Giant exchange bias field above room temperature in perovskite YbCr1−xFexO3 (x = 0.6–0.9)

Article information

Article type
Paper
Submitted
09 Oct 2023
Accepted
05 Dec 2023
First published
06 Dec 2023

Phys. Chem. Chem. Phys., 2024,26, 1284-1292

Giant exchange bias field above room temperature in perovskite YbCr1−xFexO3 (x = 0.6–0.9)

K. Zhao, D. Wang, L. Wang and S. U. Rehman, Phys. Chem. Chem. Phys., 2024, 26, 1284 DOI: 10.1039/D3CP04883G

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